Chemistry
Organic Chemistry Fundamentals
287 Questions
Organic chemistry fundamentals cover the structure, properties, and reactions of carbon containing compounds. The questions explore functional groups, isomerism, homologous series, and basic reaction mechanisms. This forms the basis of general chemistry across multiple examination formats.
Functional groupsIsomerism typesHomologous seriesCycloalkanesOrganic monomers
Organic Chemistry Fundamentals Questions
C
Correct answer
Explanation
Chloroform has the chemical formula CHCl3, consisting of one carbon, one hydrogen, and three chlorine atoms. CHCl5 is impossible (carbon can only bond to 4 atoms), CH2Cl2 is dichloromethane, and CCl4 is carbon tetrachloride.
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will match "cyclopentane"
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will match "tri-pentane"
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will match "n-pentane"
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will match "neopentane"
A,B,D
Correct answer
Explanation
The regular expression .{3,5}pentane matches any string containing between 3 and 5 characters followed by "pentane". "cyclopentane" has 5 preceding characters, "tri-pentane" has 4, and "neopentane" has 3, so all three match.
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m+j = 2r
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m+j = r
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m+2j = r
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m+3j = r
C
Correct answer
Explanation
For a 2D truss structure, the formula m + 2j = r is derived from stability conditions where m equals members, j equals joints, and r equals reaction components. This relationship determines structural determinacy.
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C5H52-
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C8H82-
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C4H42-
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C6H6
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C2H22-
B
Correct answer
Explanation
Since uranocene is U(C8H8)2.
Hence, the ligand C8H82- is present in uranocene.
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-OH, -NR2, -CH3
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-NO, -SO3H, -CHO
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-NO2, -CN, -NR2
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-NO, -SO3H, -NR2
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-OH, -NR2, -SO3H
B
Correct answer
Explanation
A monosubstituted benzene, when treated with an electrophile, undergoes electrophilic aromatic substitution reaction. Each reaction yields a disubstituted benzene as the organic product, which can be identified using the descriptors ortho, para and meta products.
Common ortho and para directing groups are:
-OH, -NR2, -CH3, -NR2, etc.
Common meta directing groups are:
-NO, -SO3H, -CHO, -NO2, -CN, etc.
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Acetonitrile
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Acetic acid
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Formic acid
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Acetaldehyde
A
Correct answer
Explanation
Methyl cyanide (CH3CN) is systematically known as acetonitrile, the simplest nitrile compound. Acetic acid is CH3COOH, a carboxylic acid. Formic acid is HCOOH, the simplest carboxylic acid. Acetaldehyde is CH3CHO, an aldehyde. Methyl cyanide contains the nitrile functional group (-CN), not carboxylic acid or aldehyde groups.
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Only 1
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1 and 3
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Only 2
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2 and 3
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All of the above
B
Correct answer
Explanation
In both the cases, only geometry changes. NH3 → NH4+NH3: sp3 hybridization, trigonal pyramidal geometry NH4+: sp3 hybridization, tetrahedral geometry H2O → H3O+H2O: sp3 hybridization, bent (V-shaped) geometryH3O+: sp3 hybridization, trigonal pyramidal geometry.
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Koch reaction
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Duff reaction
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Dakin reaction
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Kolbe reaction
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Riemer-Tiemann reaction
A
Correct answer
Explanation
This option is correct. Hydrocarboxylation of isobutene in the presence of an acid gives pivalic acid.
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Aldehydes or ketones are reduced in presence of amalgamate zinc/hydrochloric acid to form alkane.
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Aldehydes or ketones are reduced in presence of aluminium isopropoxide to form alcohol.
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Aldehydes or ketones are reduced in the presence of hydrazine to alkane.
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Cynide reduced in presence of stannous chloride with hydrochloric acid followed by hydrolysis yield aldehydes.
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Both (3) and (4) are correct
B
Correct answer
Explanation
This option is correct because when aldehydes or ketones are reduced with reagent aluminium isopropoxide it gives alcohol.
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The size of molecule
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The shape of its molecule
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The total number of atoms in its molecule
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The number of different types of atoms in its molecule
D
Correct answer
Explanation
A chemical formula represents the types of atoms in a compound and their relative proportions. For example, H2O shows hydrogen and oxygen atoms in a 2:1 ratio. Option D correctly identifies that formulas indicate different atom types present.
C
Correct answer
Explanation
Acetylene (C2H2) is an alkyne with a triple bond. It decolorizes alkaline KMnO4 due to unsaturation and forms a white precipitate of silver acetylide with ammoniacal AgNO3. Methane (C2H6 is ethane, C2H4 is ethene, C2H is not a stable hydrocarbon) do not give both reactions.
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It may have 2 double bonds and 5 rings.
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It may have 1 double bond and 1 ring.
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It may have 3 double bonds and 1 ring.
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It may have a single bond and 0 rings.
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It may have 2 double bonds and 1 ring.
C
Correct answer
Explanation
The benzene ring consists of six coplanar carbon atoms bonded by alternating double and single bonds. DoU = 4, where C = 6, N = 0, X = 0, and H = 6. 1 DoB can equal 1 ring or 1 double bond. This corresponds to benzene containing 1 ring and 3 double bonds.
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metamers
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isomers
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polymers
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monomers
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tautomers
B
Correct answer
Explanation
They have same molecular formula but different structures
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Alkaloid
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Peptone
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Steroid
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Terpene
D
Correct answer
Explanation
Terpenes are composed of isoprene units (C5H8), which are five-carbon compounds that serve as building blocks. Monoterpenes have 2 isoprene units, sesquiterpenes have 3, and diterpenes have 4. Steroids are derived from terpenes but have a fused ring structure. Alkaloids contain nitrogen and peptones are protein derivatives.
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Nitrogen
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Sulphur
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Carbon
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Oxygen
C
Correct answer
Explanation
Carbon is an essential element in all organic compounds.