Chemistry
Organic Chemistry Fundamentals
237 Questions
Organic chemistry fundamentals cover the structure, properties, and reactions of carbon containing compounds. The questions explore functional groups, isomerism, homologous series, and basic reaction mechanisms. This forms the basis of general chemistry across multiple examination formats.
Functional groupsIsomerism typesHomologous seriesCycloalkanesOrganic monomers
Organic Chemistry Fundamentals Questions
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C5H52-
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C8H82-
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C4H42-
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C6H6
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C2H22-
B
Correct answer
Explanation
Since uranocene is U(C8H8)2.
Hence, the ligand C8H82- is present in uranocene.
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square pyramid
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trigonal bipyramid
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octahedral
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pentagonal bipyramid
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none of these
D
Correct answer
Explanation
Here sp3d3 hybridisation will occur forming pentagonal bipyramid structure by 7 orbitals.
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3, 2, 1
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2, 4, 6
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1, 2, 3
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6, 4, 2
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None of these
A
Correct answer
Explanation
XeF2 in first exited form is 5s2 5p5 5d1, i.e. 3 lone pairs. Similarly XeF4 has 2 lone pairs and XeF6 has 1 lone pair.
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-OH, -NR2, -CH3
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-NO, -SO3H, -CHO
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-NO2, -CN, -NR2
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-NO, -SO3H, -NR2
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-OH, -NR2, -SO3H
B
Correct answer
Explanation
A monosubstituted benzene, when treated with an electrophile, undergoes electrophilic aromatic substitution reaction. Each reaction yields a disubstituted benzene as the organic product, which can be identified using the descriptors ortho, para and meta products.
Common ortho and para directing groups are:
-OH, -NR2, -CH3, -NR2, etc.
Common meta directing groups are:
-NO, -SO3H, -CHO, -NO2, -CN, etc.
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Be2C
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Al4C3
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CaC2
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BeC2
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Mg2C3
E
Correct answer
Explanation
Allylide – These give methyl acetylene or allylene on hydrolysis and contain C34- ions. Example: Mg2C3
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Square
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Pyramidal
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Triangular
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None of these
B
Correct answer
Explanation
Ethylamine (CH3CH2NH2) has a pyramidal structure around the nitrogen atom due to sp3 hybridization with three bond pairs and one lone pair, similar to ammonia (NH3). Square planar geometry occurs in some d8 metal complexes. Triangular planar geometry occurs in sp2 hybridized molecules like boron trifluoride. Ethylamine's nitrogen is definitely not square or triangular planar.
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Only 1
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1 and 3
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Only 2
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2 and 3
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All of the above
B
Correct answer
Explanation
In both the cases, only geometry changes. NH3 → NH4+NH3: sp3 hybridization, trigonal pyramidal geometry NH4+: sp3 hybridization, tetrahedral geometry H2O → H3O+H2O: sp3 hybridization, bent (V-shaped) geometryH3O+: sp3 hybridization, trigonal pyramidal geometry.
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The size of molecule
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The shape of its molecule
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The total number of atoms in its molecule
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The number of different types of atoms in its molecule
D
Correct answer
Explanation
A chemical formula represents the types of atoms in a compound and their relative proportions. For example, H2O shows hydrogen and oxygen atoms in a 2:1 ratio. Option D correctly identifies that formulas indicate different atom types present.
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It may have 2 double bonds and 5 rings.
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It may have 1 double bond and 1 ring.
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It may have 3 double bonds and 1 ring.
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It may have a single bond and 0 rings.
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It may have 2 double bonds and 1 ring.
C
Correct answer
Explanation
The benzene ring consists of six coplanar carbon atoms bonded by alternating double and single bonds. DoU = 4, where C = 6, N = 0, X = 0, and H = 6. 1 DoB can equal 1 ring or 1 double bond. This corresponds to benzene containing 1 ring and 3 double bonds.
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metamers
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isomers
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polymers
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monomers
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tautomers
B
Correct answer
Explanation
They have same molecular formula but different structures
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Alkaloid
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Peptone
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Steroid
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Terpene
D
Correct answer
Explanation
Terpenes are composed of isoprene units (C5H8), which are five-carbon compounds that serve as building blocks. Monoterpenes have 2 isoprene units, sesquiterpenes have 3, and diterpenes have 4. Steroids are derived from terpenes but have a fused ring structure. Alkaloids contain nitrogen and peptones are protein derivatives.
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XeF2
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Xe2O3
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XeOF2
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XeO2F2
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XeF4
B
Correct answer
Explanation
X2O3 has sp3 hybridisation, one lone pair and trigonal pyramidal geometry.
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ClF3, XeOF2, ICl3
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NH3, PH3, AsH3
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OF2, NH2-, ClO2-
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XeF2, I3-, ICl2-
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ClF3, PCl3, H3O+
A
Correct answer
Explanation
ClF3, XeOF2, ICl3 : All are T-shaped molecules.
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Chain silicates and double chain silicates
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Double chain silicates and sheet silicates
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Sheet silicates and cyclic silicates
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Cyclic silicates and chain silicates
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Cyclic silicates and double sheet silicates
D
Correct answer
Explanation
Cyclic silicates as well as chain silicates have same general formula, i.e. (SiO3)n2n-.
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P and Q
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P and R
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P and S
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Q and R
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R and S
E
Correct answer
Explanation
NF3 and H3O+: Both are pyramidal (isostructural).
NO3- and BF3: Both are trigonal planar (Isostructural).