Chemistry
Organic Chemistry Fundamentals
237 Questions
Organic chemistry fundamentals cover the structure, properties, and reactions of carbon containing compounds. The questions explore functional groups, isomerism, homologous series, and basic reaction mechanisms. This forms the basis of general chemistry across multiple examination formats.
Functional groupsIsomerism typesHomologous seriesCycloalkanesOrganic monomers
Organic Chemistry Fundamentals Questions
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Chain silicates and double chain silicates
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Double chain silicates and sheet silicates
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Sheet silicates and cyclic silicates
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Cyclic silicates and chain silicates
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Cyclic silicates and double sheet silicates
D
Correct answer
Explanation
Both cyclic silicates as well as chain silicates have the same general formula: (SiO3)n2n-
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A only
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B only
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C only
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A and B
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A, B and C
A
Correct answer
Explanation
Constitutional or Structural isomerism is a form of isomerism in which molecules with the same molecular formula have bonded together in different orders, i.e. they each have a different structural formula.
⇒ Propionaldehyde or propanal (CH3CH2CHO) is the organic compound with the molecular formula C6H6O.
⇒ 1-Propanol (CH3CH2CH2OH) is the organic compound with the molecular formula C6H8O.
Propanal and 1-Propanol molecular formula are different so they are not able to show the Constitutional or Structural isomerism.
B
Correct answer
Explanation
In a homologous series, each successive member differs by one -CH2- unit (called a methylene group) when moving up or down the series. This constant difference of 14 atomic mass units gives the series its characteristic incremental physical and chemical properties. -CH, -CH4, and -CH3CH2 are not the repeating units.
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CnH2n
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CnH2n+2
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CnH2n-2
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CnH2n-4
B
Correct answer
Explanation
Alkanes are saturated hydrocarbons with the general formula CnH2n+2, where each carbon atom forms four single bonds. For alkenes it's CnH2n, for alkynes it's CnH2n-2, and option D doesn't represent any standard homologous series. The '+2' accounts for the extra hydrogens needed for saturation.
D
Correct answer
Explanation
The given compounds CH4, C2H6, and C3H8 are alkanes following the general formula CnH2n+2. The homologous series continues with C4H10 (butane) and C5H12 (pentane). Therefore, the fifth member is C5H12.
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CnH2n
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CnH2n+2
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CnH2n-2
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CnH2n-4
A
Correct answer
Explanation
Alkenes are hydrocarbons with one carbon-carbon double bond. This reduces the hydrogen count by 2 compared to alkanes, giving the general formula CnH2n where n is the number of carbon atoms.
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CnH2n+2
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CnH2n-2
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CnH2n
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CnH2n- 4
B
Correct answer
Explanation
Alkynes contain a carbon-carbon triple bond. This triple bond reduces the hydrogen count by 4 compared to alkanes (CnH2n+2), resulting in the general formula CnH2n-2 where n is the number of carbon atoms.
D
Correct answer
Explanation
Pentane is a 5-carbon alkane, and all alkanes follow the formula CnH2n+2. For n=5, this gives C5H12. The other options represent ethane, propane, and butane respectively.
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2, 3 and 4 (Tetrahedral only).
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2, 4 (Tetrahedral only) and 6.
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2, 3 and 4 (Square planar only).
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2, 4 (Tetrahedral and square planar).
A
Correct answer
Explanation
Geometrical isomerism requires restricted ligand arrangement with cis/trans positioning. Tetrahedral complexes (CN=4) never show it because all ligands are adjacent. Linear (CN=2) and trigonal planar (CN=3) geometries lack the spatial arrangement needed. Square planar (CN=4) and octahedral (CN=6) complexes do show geometrical isomerism.
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Geometrical isomers have same physical and chemical properties.
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In cis-isomers, the two identical ligands occupy the positions diagonal to each other.
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In trans-isomers, the two identical ligands occupy the positions adjacent to each other.
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Geometrical isomerism is a type of stereo isomerism.
D
Correct answer
Explanation
Geometrical isomerism is a subtype of stereoisomerism where isomers differ in spatial arrangement but not in bonding connectivity. Geometrical isomers have different physical properties. Cis-isomers have identical ligands adjacent; trans-isomers have them opposite.
C
Correct answer
Explanation
EDTA is a hexadentate ligand that wraps around the metal ion. In [Co(edta)]-, EDTA occupies all six coordination sites in octahedral geometry. This arrangement creates a chiral center, giving two enantiomers (optical isomers).
B
Correct answer
Explanation
Stereoisomerism has two main types: geometrical isomerism (cis/trans, fac/mer) and optical isomerism (enantiomers). All stereoisomers fall into these two categories based on how they differ spatially.
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Bent
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Trigonal planar
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Tetrahedral
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Pyramidal
D
Correct answer
Explanation
In geometry, a pyramid is a polyhedron formed by connecting a polygonal base and a point called the apex. Each base edge and apex form a triangle. It is a conic solid with polygonal base, like NH3.
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1 and 2
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1, 2 and 3
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2 and 3
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2 and 4
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3, 4 and 5
E
Correct answer
Explanation
CO32- (32 electrons) and NO32- (32 electrons) are isoelectronic species.
CO2 (22 electrons) and N3- (22 electrons) are isoelectronic species.
NO2- (24 electrons) and O3 (24 electrons) are isoelectronic species.
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4<font size="2">-</font>carbon compound
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3<font size="2">-</font>carbon compound
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2<font size="2">-</font>carbon compound
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None of these
A
Correct answer
Explanation
Malic acid is a 4-carbon compound.