Tag: nitrogen and sulfur

Questions Related to nitrogen and sulfur

$NH _4Cl, NH _4NO _3$ and $(NH _4) _2CO _3$ gives  $NH _3$ gas on heating.

chemistry nitrogen and sulfur ammonia and fertilizers preparation of ammonia-laboratory method and haber's process ammonia

  1. True

  2. False

Show answer
Correct Option: B
Explanation:

Reaction:
$NH _4NO _3\rightarrow N _2O+2H _2O$
$NH _4Cl\rightarrow NH _3+HCl$
$(NH _4) _2CO _3\rightarrow 2 NH _3 + H _2O + CO _2$

Give the balanced reaction for the manufacture of the ammonia gas.

chemistry nitrogen and sulfur ammonia and fertilizers preparation of ammonia-laboratory method and haber's process ammonia

  1. $3{ N } _{ 2 }+3{ H } _{ 2 }\rightarrow 6{ NH } _{ 3 }$

  2. ${ N } _{ 2 }+3{ H } _{ 2 }\rightarrow 2{ NH } _{ 3 }$

  3. ${ N } _{ 2 }+3{ H } _{ 2 }\rightarrow { NH } _{ 3 }$

  4. ${ N } _{ 2 }+6{ H } _{ 2 }\rightarrow 4{ NH } _{ 3 }$

Show answer
Correct Option: B
Explanation:

${ N } _{ 2 }+3{ H } _{ 2 }\rightarrow 2{ NH } _{ 3 }$
In the manufacture of ammonia process employed is Haber-Bosch which occurs in the presence of catalyst at high temperature and high pressure.

An alkaline gas, which produces dense white fumes when reacted with HCl gas is________.

chemistry nitrogen and sulfur ammonia and fertilizers preparation of ammonia-laboratory method and haber's process ammonia

  1. ammonia

  2. chlorine

  3. nitrogen

  4. oxygen

Show answer
Correct Option: A
Explanation:

An alkaline gas which produces dense white fumes when reacted with HCl gas is ammonia and fumes are of compound ammonium chloride.

In the manufacture of ammonia, the catalyst used is :

chemistry nitrogen and sulfur ammonia and fertilizers preparation of ammonia-laboratory method and haber's process ammonia

  1. magnesium oxide

  2. silver

  3. gold

  4. nickel

Show answer
Correct Option: A
Explanation:

Several catalysts are being utilized. The catalyst is iron containing iron oxide, magnesium oxide, aluminium oxide and ruthenium on carbon.

Which of the following reaction represents the balanced form of conversion of Ca to ammonia?

chemistry nitrogen and sulfur ammonia and fertilizers preparation of ammonia-laboratory method and haber's process ammonia

  1. ${ 2NH } _{ 4 }Cl+Ca\left( OH \right) _{ 2 }\xrightarrow { \triangle } { CaCl } _{ 2 }+{ 2H } _{ 2 }O+{ 2NH } _{ 3 }$

  2. ${ NH } _{ 4 }Cl+Ca\left( OH \right) _{ 2 }\xrightarrow { \triangle } { CaCl } _{ 2 }+{ 2H } _{ 2 }O+{ NH } _{ 3 }$

  3. ${ 2NH } _{ 4 }Cl+3Ca\left( OH \right) _{ 2 }\xrightarrow { \triangle } 3{ CaCl } _{ 2 }+{ 2H } _{ 2 }O+{ 2NH } _{ 3 }$

  4. ${ 4NH } _{ 4 }Cl+Ca\left( OH \right) _{ 2 }\xrightarrow { \triangle } 2{ CaCl } _{ 2 }+{ 2H } _{ 2 }O+{ 2NH } _{ 3 }$

Show answer
Correct Option: A

Equation for the following reaction.
$Cu+{ xHNO } _{ 3 }\rightarrow Cu\left( { NO } _{ 3 } \right) _{ 2 }+{ 2H } _{ 2 }O+{ 2NO } _{ y }$
Find the value of $x$ and $y$.

chemistry nitrogen and sulfur ammonia and fertilizers preparation of ammonia-laboratory method and haber's process ammonia

  1. $x=4, y= 2$

  2. $x=1, y= 2$

  3. $x=2, y= 2$

  4. $x=4,, y= 1$

Show answer
Correct Option: A
Explanation:

$Cu+{ 4HNO } _{ 3 }\rightarrow Cu\left( { NO } _{ 3 } \right) _{ 2 }+{ 2H } _{ 2 }O+{ 2NO } _{ 2 }$

$NH _4CI, NH _4NO _3$ and $(NH _4) _2CO _3$ gives $NH _3$ gas on heating.

chemistry nitrogen and sulfur ammonia and fertilizers preparation of ammonia-laboratory method and haber's process ammonia

  1. True

  2. False

Show answer
Correct Option: B
Explanation:

Reaction:
$NH _4NO _3\rightarrow N _2O+2H _2O$
$NH _4Cl\rightarrow NH _3+HCl$
$(NH _4) _2CO _3\rightarrow 2 NH _3 + H _2O + CO _2$

Which of the following is/are correct?

chemistry nitrogen and sulfur ammonia and fertilizers preparation of ammonia-laboratory method and haber's process ammonia

  1. Hydrolysis of $NCl _3$ gives $NH _3$ and $HClO$

  2. $NH _3$ is less stable than $PH _3$

  3. $NH _3$ is a weak reducing agent compared to $PH _3$

  4. Nitric oxide is paramagnetic

Show answer
Correct Option: A,C,D
Explanation:

A) $NCl _3$ is hydrolyzed by hot water to release ammonia and hypochlorous acid.
 $NCl _3 + 3H _2O\rightarrow NH _3 + 3HOCl$

B)  $NH _3$ is less stable than $PH _3$, because $NH _3$ is more stable than $PH _3$ due to inter molecular hydrogen bonding.
C) $NH _3$ is a weak reducing agent compared to $PH _3$, because from $NH _3$ to $PH _3$ reducing nature increases down the group.
D) Nitric oxide is paramagnetic, because it is having unpaired electrons.
Hence, options A,C & D are correct.

Ammonia is not a product in the :

chemistry nitrogen and sulfur ammonia and fertilizers preparation of ammonia-laboratory method and haber's process ammonia

  1. hydrolysis of nitrolim

  2. hydrolysis of aluminium nitride

  3. decomposition of ammonium nitrite

  4. hydrolysis of urea

Show answer
Correct Option: C
Explanation:

$NH _3NO _3\rightarrow N _2O+2H _2O$
Nitrous oxide is produced after decomposition of ammonium nitrite instead of ammonia.

 Which compound does not give ammonia gas on reaction with water ?

chemistry nitrogen and sulfur ammonia and fertilizers preparation of ammonia-laboratory method and haber's process ammonia

  1. $ \mathrm{M}\mathrm{g} _{3}\mathrm{N} _{2}$

  2. $ \mathrm{A}\mathrm{l}\mathrm{N}$

  3. $\mathrm{C}\mathrm{a}\mathrm{C}\mathrm{N} _{2}$

  4. $\mathrm{C}\mathrm{a}(\mathrm{C}\mathrm{N}) _{2}$

Show answer
Correct Option: D
Explanation:
$Mg _3N _2 + 6H _2O \longrightarrow3Mg(OH) _2 + 2NH _3$

$AlN + 3H _2O \longrightarrow NH _3 + Al(OH) _3$

$2H _2O + Ca(CN) _2 \longrightarrow Ca(OH) _2 + 2HCN$

$CaCN _{2} + 3H _{2}O\longrightarrow$ $CaCO _{3} + 2NH _{3}$

$Ca(CN) _2$ does not produce ammonia on reacting with water.