Mixtures and Alligation Questions

Multiple choice
  1. $50mm$
  2. $60mm$
  3. $70mm$
  4. $40mm$
Reveal answer Fill a bubble to check yourself
B Correct answer
Multiple choice
  1. $\dfrac {1}{5}, \dfrac {4}{5}$
  2. $\dfrac {1}{3}, \dfrac {2}{3}$
  3. $\dfrac {1}{7}, \dfrac {6}{7}$
  4. $\dfrac {1}{9}, \dfrac {8}{9}$
Reveal answer Fill a bubble to check yourself
A Correct answer
Multiple choice
  1. 0.628

  2. 0.872

  3. 0.267

  4. 0.834

Reveal answer Fill a bubble to check yourself
C Correct answer
Explanation

Raoult's Law: P_A = x_A * P_A_pure. Total pressure P = x_A * P_A_pure + (1-x_A) * P_B_pure. Mole fraction in vapor y_A = (x_A * P_A_pure) / P. Given y_A = 0.35, P_A_pure = 577, P_B_pure = 390. 0.35 = (x_A * 577) / (x_A * 577 + (1-x_A) * 390). 0.35 = 577x_A / (187x_A + 390). 0.35(187x_A + 390) = 577x_A. 65.45x_A + 136.5 = 577x_A. 136.5 = 511.55x_A. x_A = 0.2668.

Multiple choice
  1. 300 mm Hg

  2. 250 mm Hg

  3. 199.4 mm Hg

  4. 180.6 mm Hg

Reveal answer Fill a bubble to check yourself
C Correct answer
Explanation

Moles of C6H6 = 936 / 78 = 12. Moles of C7H8 = 736 / 92 = 8. Total moles = 20. Mole fraction of C6H6 (X_B) = 12/20 = 0.6. Pressure p = 179(0.6) + 92 = 107.4 + 92 = 199.4.

Multiple choice
  1. $0.162$
  2. $0.675$
  3. $0.325$
  4. $0.486$
Reveal answer Fill a bubble to check yourself
C Correct answer
Explanation

The two substances have approximately equal mole amounts, so their liquid-phase mole fractions are both about 0.5. Their partial pressures are therefore about 207.5 mm Hg and 100 mm Hg, giving a chloroform vapor mole fraction of 100/(207.5 + 100) = 0.325.

Multiple choice
  1. $H_2O=$ 35%
  2. $H_2O=$ 22%
  3. $H_2O=$ 29%
  4. $H_2O=$ 71%
Reveal answer Fill a bubble to check yourself
C Correct answer
Explanation

Dalton's law for steam distillation: P_total = P_water + P_chlorobenzene. 740.2 = 530.1 + P_chlorobenzene => P_chlorobenzene = 210.1. Mass ratio = (P1 * M1) / (P2 * M2). Molar masses: H2O=18, Chlorobenzene=112.5. Mass ratio = (530.1 * 18) / (210.1 * 112.5) = 9541.8 / 23636.25 = 0.403. % H2O = 0.403 / 1.403 = 28.7%.