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Multiple choice chemistry oxidation- reduction reactions redox reactions and electrode processes redox and electrode processes applications of redox reaction

In a Daniell cell:

  1. The chemical energy liberated during the redox reaction is converted to electrical energy

  2. The electrical energy of the cell is converted to chemical energy

  3. The energy of the cell is utilised in conduction of the redox reaction

  4. The potential energy of the cell is converted into electrical energy
Reveal answer Fill a bubble to check yourself
A Correct answer
Explanation

A galvanic cell is an electrochemical cell that derives electrical energy from spontaneous redox reactions taking place within the cell. It generally consists of two different metals connected by a salt bridge, or individual half-cells separated by a porous membrane. Daniel cell is a galvanic cell.

Daniel cell has Zn as anode and Cu as cathode. The reactions of Daniel cell are,

At anode(Oxidation),

$Zn(s)\rightarrow Zn^{2+}(aq)+2e^{-}$

At cathode(Reduction),

$Cu^{2+}(aq)+2e^{-}\rightarrow Cu(s)$

Hence overall reaction is,

$Zn(s)+Cu^{2+}(aq)\rightarrow Zn^{2+}(aq)+Cu(s)$

Here the chemical energy is liberated when the redox reaction takes place in the cell and it is converted into electrical energy.

Multiple choice chemistry oxidation- reduction reactions redox reactions and electrode processes redox and electrode processes applications of redox reaction

Which one is not correct for e.m.f. of a galvanic cell?

  1. $E _{cell} = E _{OP _{anode}} + E _{RP _{cathode}}$
  2. $E _{cell} = E _{OP _{LHS}} + E _{RP _{RHS}}$
  3. $E _{cell} =$ higher oxidation potential - lower oxidation potential
  4. $E _{cell} =$ lower oxidation potential - higher oxidation potential
Reveal answer Fill a bubble to check yourself
A,B,C Correct answer
Explanation

The correct expressions for the standard cell potentials of a galvanic cell are as given below.
$E _{cell} = E _{OP _{anode}} + E _{OP _{cathode}}$
$E _{cell} = E _{OP _{LHS}} + E _{OP _{RHS}}$
$E _{cell} =$lower oxidation potential $-$ higher oxidation potential.
Thus, only option D is correct and options A to C are incorrect.

Multiple choice chemistry oxidation- reduction reactions redox reactions and electrode processes redox and electrode processes applications of redox reaction

Identify the true statement regarding Daniel cell:

  1. Zinc ions flows across salt bridge

  2. ${K}^{+}$ ions move from salt bridge to $Cu/{Cu}^{+2}$ half cell

  3. Oxidation takes place at copper electrode

  4. Flow of current takes place from copper electrode to zinc electrode
Reveal answer Fill a bubble to check yourself
D Correct answer
Explanation

Daniell cell is  perform the spontaneous redox reaction between zinc and cupric ions to produce an electric current. It consists of two half-cells. The  left half cell contains a zinc metal electrode dipped in $ZnSO _4$ solution.The half right half cell consists of copper metal electrode in a solution $CuSO _4$. The half-cells are joined by a salt bridge that prevents the mixing of the solution.
In Daniel cell flow of current takes place from copper electrode to zinc electrode.
Hence option D is correct.

Multiple choice chemistry oxidation- reduction reactions redox reactions and electrode processes redox and electrode processes applications of redox reaction

For the galvanic cell, $Cu|Cu^{2+}||Ag^+|Ag$. Which of the following observations is not correct?

  1. Cu acts as anode and Ag acts as cathode

  2. Ag electrode loses mass and Cu electrode gains mass
  3. Reaction at anode, $Cu\rightarrow Cu^{2+}+2e^-$

  4. Copper is more reactive than silver
Reveal answer Fill a bubble to check yourself
B Correct answer
Explanation

Redox reactions are reactions in which both oxidation and reduction takes place together. In a Galvanic cell oxidation occurs at anode and reduction occurs at cathode. Here $Cu$ is an anode and $Ag$ is a cathode. As in Oxidation, the electrons get released to form aqueous ions in the solution and hence reduces the mass of the electrode as the electrons are released from the electrode. Here,$Cu$ electrode loses mass. Similarly,the released electrons are gained by silver ions i.e $Ag^ { +} $ and the electrode mass of $Ag$ gets increased. Hence, B is the wrong option.

Multiple choice chemistry classification of elements- the periodic table periodic trends in physical properties properties and trend trends in periodic table electronic configuration and valency electron configuration

On the Mulliken scale, the average of ionization potential and electrons affinity is known as _____(electronegativity/affinity).

  1. electronegativity

  2. electroneaffinity

  3. electropositivity

  4. none
Reveal answer Fill a bubble to check yourself
A Correct answer
Explanation

On Mulliken scale, the average of ionization potential and electrons affinity is known as electronegativity.

Multiple choice chemistry classification of elements- the periodic table periodic trends in physical properties properties and trend trends in periodic table electronic configuration and valency electron configuration

If the E.N. value of Nitrogen in the pauling scale is 3.0, then he value in mulliken scale will be

  1. $11.2$
  2. $22.4$
  3. $8.4$
  4. $3.0$
Reveal answer Fill a bubble to check yourself
C Correct answer
Explanation

The Mulliken electronegativity (M) is related to the Pauling scale (P) by the approximate relation M = 2.8 * P^2 + 0.77 * P, or more commonly in introductory chemistry, M = 2.8 * P. Using the standard conversion factor of 2.8, 3.0 * 2.8 = 8.4.

Multiple choice chemistry classification of elements- the periodic table periodic trends in physical properties properties and trend trends in periodic table electronic configuration and valency electron configuration

Which of the following is the correct order of hydrated radii?

  1. $Li^{+} < Na^{+} < K^{+} < Rb^{+} < Cs^{+}$
  2. $Rb^{+} < Na^{+} < Li ^{+} < Cs^{+} < K^{+}$
  3. $Cs^{+} < Rb^{+} < K^{+} < Na ^{+}< Li^{+}$
  4. $Li^{+} < K^{+} < Na^{+} < Rb ^{+} < Cs ^{+}$
Reveal answer Fill a bubble to check yourself
A Correct answer
Multiple choice chemistry classification of elements- the periodic table periodic trends in physical properties properties and trend trends in periodic table electronic configuration and valency electron configuration

Electronegativity of $F$ on Pauling's scale is 4.0. The value on Mulliken's scale is:

  1. $11.2$
  2. $14.4$
  3. $16.8$

  4. None of these
Reveal answer Fill a bubble to check yourself
A Correct answer
Explanation

Mulliken proposed that the arithmetic mean of the first ionization energy (I) and the electron affinity (Eea) should be a measure of the tendency of an atom to attract electrons.
$X= \dfrac{E _i + E _{Ea}}{2}$
Electronegativity of $F$ on Mulliken's scale is hence $11.2$

Multiple choice chemistry classification of elements- the periodic table periodic trends in physical properties properties and trend trends in periodic table electronic configuration and valency electron configuration

EN(mulliken scale) of the element (A) is $E _1$ and IP is $E _2$. Hence, EA will be:

  1. $2E _1 - E _2$
  2. $E _1 - E _2$
  3. $E _1 - 2E _2$
  4. $(E _1 + E _2)/2$
Reveal answer Fill a bubble to check yourself
A Correct answer
Explanation

As we know,
$\displaystyle EN = \frac{(IP) + (EA)}{2}$ 


$EA = 2 EN - IP$

$EA = 2E _1 - E _2$

Multiple choice chemistry classification of elements- the periodic table periodic trends in physical properties properties and trend trends in periodic table electronic configuration and valency electron configuration

The ionic radii of ${Rb}^{+}$ and ${I}^{-}$ are $1.46$ and $2.16$ $\mathring { A } $, respectively. The most probable type of structure exhibited by it is

  1. $CsCl$ type
  2. $NaCl$ type
  3. $ZnS$ type
  4. $Ca{F} _{2}$ type
Reveal answer Fill a bubble to check yourself
B Correct answer
Explanation

The radius ratio is calculated as r+/r- = 1.46 / 2.16 = 0.676. A radius ratio between 0.414 and 0.732 indicates an octahedral coordination geometry, which corresponds to the NaCl crystal structure.