Tag: chemistry

Questions Related to chemistry

Statement I: Methane is defined as a compound
Statement II: Methane can be broken down chemically

  1. Statement 1 and Statement 2 are correct and Statement 2 is the correct explanation of Statement 1

  2. Both the Statement 1 and Statement 2 are correct and Statement 2 is not the correct explanation of Statement 1

  3. Statement 1 is correct but Statement 2 is not correct.

  4. Statement 1 is not correct but Statement 2 is correct.

  5. Both the Statement 1 and Statement 2 are not correct.


Correct Option: A
Explanation:

Statement I: methane is defined as a compound
statement II: Methane can be broken down chemically
Statement 1 and Statement 2 are correct and Statement 2 is the correct explanation of Statement 1.
Note: Compounds are defined as substances of definite compositions which can be decomposed into two or more substances by a simple chemical process.

The correct composition of water gas is :

  1. mixture of $H _2$ and $CO$

  2. mixture of $N _2$ and $CO$

  3. mixture of $He$ and $CO$

  4. mixture of $O _2$ and $CO$


Correct Option: A
Explanation:

Water gas is produced from synthesis gas, which is composed of carbon monoxide and hydrogen. Syngas is a useful product, but requires careful handling due to its flammability and the risk of carbon monoxide poisoning

Reaction of methane with halogens under appropriate conditions is called as :

  1. Halogenation

  2. Free radical halogenation

  3. Methylation

  4. Chlorination


Correct Option: B
Explanation:

Methane reacts with halogens given appropriate conditions as follows:

${X} _{2} + UV \rightarrow  2 X \cdot$

$X \cdot + C{H} _{4} \rightarrow HX + C{H} _{3} \cdot$

$C{H} _{3} \cdot + {X} _{2} \rightarrow C{H} _{3}X + X \cdot$

where $X$ is a halogen: fluorine $\left(F\right)$, chlorine $\left(Cl\right)$, bromine $\left(Br\right)$, or iodine $\left(I\right)$. This mechanism for this process is called free radical halogenation.

Which are the gases formed in a biogas plant?

  1. $CO, CH _{4}$

  2. $CH _{4}, CO _{2}$

  3. $CO _{2}, O _{2}$

  4. $N _{2}, S _{2}$


Correct Option: A

Which of the following is not a derivative of carboxylic acids ?

  1. anhydrides

  2. esters

  3. amines

  4. amides


Correct Option: C
Explanation:

C
Rest all are derivatives of carboxylic acids.And directly by the hydrolysis of amines carboxylic acids cannot be formed.

Which of the following cannot be named as a derivative of $CH _{3}COOH$?

  1. $CH _{3}CH _{2}COOH$

  2. $(CH _{3}) _{2}CHCOOH$

  3. $HCOOH$

  4. $(CH _{3}) _{3}CCOOH$


Correct Option: C
Explanation:

Option A, B and D can be derived from $CH _3 COOH$ while option C, i.e., $HCOOH$ cannot be derived from $CH _3COOH$ as $HCOOH$ has one carbon less than $CH _3COOH$.


Option C is correct.

Which of the following statements is wrong?

  1. For the synthesis of esters from carboxylic acids and alcohols, we can often use a base as a catalyst.

  2. For the synthesis of esters from carboxylic acids and alcohols, we can often use an additional acid as a catalyst.

  3. For the alkaline hydrolysis of carboxylic esters, we need to use an excess of base.

  4. For the hydrolysis of carboxylic esters under acidic conditions, we need only a catalytic amount of an additional acid.


Correct Option: A

With which of the following can ethyl ethanoate not undergo a substitution reaction?

  1. $CH _3CO _2Na$

  2. aqueous $NaOH$

  3. $CH _3OH$, $H^+$

  4. aqueous $NH _3$


Correct Option: A

Amides and acid chlorides are:

  1. organic functional group

  2. functional derivative of carboxylic acid

  3. both $A$ and $B$

  4. none of these


Correct Option: C
Explanation:

Amides and Acid chlorides are organic Functional group and functional derivative of carboxylic acid. Amide has general formula $\displaystyle  R - \underset {   \underset {\displaystyle O}{||}  }{C} - NH _2  $. Carboxylic acid has general formula $\displaystyle  R - \underset {   \underset {\displaystyle O}{||}  }{C} - OH  $. An example of amide is acetamide $\displaystyle  CH _3 - \underset {   \underset {\displaystyle O}{||}  }{C} - NH _2   $. An example of carboxylic acid is acetic acid $\displaystyle  CH _3 - \underset {   \underset {\displaystyle O}{||}  }{C} - OH  $. Acid chloride has general formula $\displaystyle  R - \underset {   \underset {\displaystyle O}{||}  }{C} - Cl  $.  An example of acid chloride is acetyl chloride $\displaystyle  CH _3 - \underset {   \underset {\displaystyle O}{||}  }{C} - Cl  $. 

As the molecular weight increases the boiling point of carboxylic acid:

  1. increases

  2. decreases

  3. remain same

  4. none of the above


Correct Option: A
Explanation:

As the molecular weight increases the boiling point of carboxylic acid increases. Lower aliphatic carboxylic acids (upto 9 C atoms) are liquids, the higher members are wax like solids.