Tag: heat and thermodynamics

Questions Related to heat and thermodynamics

When an ideal diatomic gas is heated at a constant pressure, the fraction of the heat energy supplied which increases the internal energy of the gas is

  1. $\dfrac {2}{5}$

  2. $\dfrac {3}{5}$

  3. $\dfrac {3}{7}$

  4. $\dfrac {5}{7}$


Correct Option: D
Explanation:

$Th\quad fraction\quad is\quad \frac { \triangle V }{ \triangle Q } \quad =\quad \frac { { _{ n }{ C } _{ v } }\triangle T }{ { _{ n }{ C } _{ p } }\triangle T } \ \frac { \triangle V }{ \triangle Q } =\frac { { C } _{ V } }{ { C } _{ P } } \quad =\quad \frac { 1 }{ Y } \ as\quad we\quad know\quad y\quad =\quad { C } _{ P }/{ C } _{ V }\ y\quad for\quad diatomatic\quad gas\quad :\quad \ { C } _{ P }\quad of\quad diatometic\quad gas\quad :\quad \frac { 7 }{ 2 } \ { C } _{ V }\quad of\quad diatometic\quad gas\quad :\quad \frac { 5 }{ 2 } \ y\quad =\quad \frac { { C } _{ P } }{ { C } _{ V } } =\frac { 7/2 }{ 5/2 } =\frac { 7 }{ 5 } \ \frac { \triangle V }{ \triangle Q } =\frac { 1 }{ y } =\frac { 1 }{ 7/5 } =\frac { 5 }{ 7 } \quad (D)$

For an ideal gas, the heat capacity at constant pressure is larger than that at constant volume because

  1. positive work is done during expansion of the gas by the external pressure

  2. positive work is done during expansion by the gas against external pressure

  3. positive work is done during expansion by the gas against intermolecular forces of attraction

  4. more collisions occur per unit time when volume is kept constant


Correct Option: B
Explanation:

When  heat  is  supplied  at  constant  volume,  temperature  increases accordingly  to  the  ideal  gas  equation.

$P=\dfrac { nRT }{ V } $

as  V  is  constant  and  T  is  increasing,  pressure  will  also  increase.

Than at constant pressure  as temperature is increase volume increases, resulting in expansion of the gas, resulting in positive work, Hence the heat given is used up for expansion and then to increases the internal energy . The heat capacity at constant pressure is larger.