Which one of the following reactions is an example of auto-catalysis ?
- $2{ AsH } _{ 3 }(s)\rightarrow 2As(s)+3{ H } _{ 2 }(g)$
- ${ N } _{ 2 }(g)\rightarrow 3{ H } _{ 2 }(g)\overset { Fe(g) }{ \rightarrow } 2N{ H } _{ 3 }(g)$
- ${ 2SO } _{ 2 }(g)\rightarrow { O } _{ 2 }(g)\overset { NO(g) }{ \rightarrow } 2S{ O } _{ 3 }(g)$
- ${ C } _{ 12 }{ H } _{ 22 }{ O } _{ H }(l)+{ H } _{ 2 }O(l)\overset { { H }^{ - }(l) }{ \rightarrow } { C } _{ 6 }{ H } _{ 12 }{ O } _{ 6 }(l){ HC } _{ 6 }{ H } _{ 12 }{ O } _{ 6 }(l)$
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Correct answer
Explanation
Auto-catalysis is defined as the reaction that is catalyzed by one of its product. in auto-catalysis product of reaction acts as a catalyst for the reaction. In auto-catalysis the initial rate of reaction rises as the catalytic product is formed instead of decreasing steadily.
for example: the free arsenic produced by decomposition of arsine auto catalyses the reaction. The thermal decomposition of Arsine produces arsenic and hydrogen. 2AsH3 forms 2As + 3H2