Na3AlF6 (cryolite) is used in the Hall-Heroult process for aluminum extraction because it dissolves Al2O3 at much lower temperatures (≈1000°C) than pure Al2O3 would melt (>2000°C), making electrolysis feasible. CaF2 is used as a flux in steelmaking, CaCl2 is a drying agent, and SiO2 is a component of the cell lining but not the flux.