Tag: nitrogen and sulfur

Questions Related to nitrogen and sulfur

Multiple choice chemistry nitrogen and sulfur ammonia-properties and uses ammonia compounds of nitrogen - ammonia

When $Na$ reacts with liquid $NH _3$ the following substance is formed: 

  1. $[Na(NH _3) _x]^- $
  2. $ [e(NH _3 ) _y]^-$
  3. $NaNH _2$
  4. $Na _xNH _{3y}$
Reveal answer Fill a bubble to check yourself
B Correct answer
Explanation

Sodium (Na) dissolves in liquid ammonia ($NH _3$) solution to form a blue colored solution characteristic of a solvated electron in liquid ammonia which is conducting in nature due to presence of solvated electrons.

Reaction is  $ Na + (x+y)NH _3\rightarrow Na(NH _3) _x + (e(NH _3) _y)^-$
So B is correct answer. 

Multiple choice chemistry nitrogen and sulfur ammonia-properties and uses ammonia compounds of nitrogen - ammonia

$\displaystyle Al{ Cl } _{ 3 }\left( aq \right) +{ NH } _{ 3 }\left( aq \right) + { H } _{ 2 }O\rightarrow $
Which of the following is one of the products obtained from the reaction above?

  1. $\displaystyle AlN$
  2. $\displaystyle Al{ H } _{ 3 }$
  3. $\displaystyle Al$
  4. $\displaystyle { Al\left( { NO } _{ 3 } \right) } _{ 3 }$
  5. $\displaystyle { Al\left( OH \right) } _{ 3 }$
Reveal answer Fill a bubble to check yourself
E Correct answer
Explanation

${ AlCl } _{ 3 }+3{ NH } _{ 3 }+3{ H } _{ 2 }O\rightarrow Al\left( OH \right) _{ 3 }+3{ NH } _{ 4 }Cl$

Multiple choice chemistry nitrogen and sulfur ammonia-properties and uses ammonia compounds of nitrogen - ammonia

When excess of ammonia is used:


 $3Cl _2+8NH _3$$\longrightarrow$$A+B$

When excess of chlorine is used:

$3Cl _2+4NH _3$$\longrightarrow$$C+D$

The oxidation state of nitrogen in compound $D$ is:

  1. $0$
  2. $+3$
  3. $-3$
  4. $+1$
Reveal answer Fill a bubble to check yourself
B Correct answer
Explanation

When excess chlorine reacts with ammonia (3Cl2 + 4NH3), the products are nitrogen trichloride (NCl3) and HCl. In NCl3, nitrogen is bonded to three more electronegative chlorine atoms, giving nitrogen an oxidation state of +3.

Multiple choice chemistry nitrogen and sulfur ammonia-properties and uses ammonia compounds of nitrogen - ammonia

An alkaline earth metal $(M)$ dissolves in liquid ammonia forming a deep blue-black solution. The reaction involved is:

  1. $M + 2NH _{3} \rightarrow M(NH _{2}) _{2} + H _{2}$
  2. $M + xNH _{3} \rightarrow [M(NH _{3}) _{x}]$
  3. $M + 2NH _{4}OH \rightarrow M(OH) _{2} + 2NH _{3}$
  4. $M + (x + 2y) NH _{3}\rightarrow [M(NH _{3}) _{x}]^{2+} + 2[e(NH _{3}) _{y}]^{-}$. (e represents electron)
Reveal answer Fill a bubble to check yourself
D Correct answer
Explanation

An alkaline earth metal $(M)$ dissolves in liquid ammonia forming a deep blue-black solution. The reaction involved is $M + (x + 2y) NH _{3}\rightarrow [M(NH _{3}) _{x}]^{2+} + 2[e(NH _{3}) _{y}]^{-}$ (e represents electron).
An alkaline earth metal $(M)$ will lose two electrons to form $M^{2+}$ ions.
$M \rightarrow M^{2+}+2e^-$
Both $M^{2+}$ ions and electrons are solvated (surrounded by ammonia molecules to form $[M(NH _{3}) _{x}]^{2+} + 2[e(NH _{3}) _{y}]^{-}$).

Multiple choice chemistry nitrogen and sulfur ammonia-properties and uses ammonia compounds of nitrogen - ammonia

The organic compound which was first prepared in the laboratory ?

  1. Acetic acid

  2. Methane

  3. Urea

  4. All of these

Reveal answer Fill a bubble to check yourself
C Correct answer
Explanation

Urea was first discovered in urine in 1727 by the Dutch scientist Herman Boerhaave, This was the first time an organic compound was artificially synthesized from inorganic starting materials, without the involvement of living organisms.

Multiple choice chemistry nitrogen and sulfur ammonia-properties and uses ammonia compounds of nitrogen - ammonia

Select the correct options about the solubility of the following species in $ H _2O$ and $ NH _3 $(aq).
$AgF, AgCN, AgCl, Agl, CaF _2, CaCl _2 $ :

  1. $AgF$ and $CaCl _2 $ are soluble in $H _2O$
  2. $AgCN$ and $AgCl$ are soluble in $NH _3$
  3. $AgI$ and $CaF _2$ are soluble in $ H _2O $ and $ NH _3 $ (aq) both
  4. None of these

Reveal answer Fill a bubble to check yourself
A,B Correct answer
Explanation

A. $AgF$ and $CaCl _2$ are polar compounds. Hence, they are soluble in water which is a polar solvent. Thus, the option A is correct.

B. $AgCN$ and $AgCl$ form complexes with ammonia as ammonia is a very good ligand. Hence, $AgCN$ and $AgCl$ are soluble in ammonia. Thus, the option B is correct.

C. $CaF _2$ and $AgI$ are insoluble in water. Thus, the option C is incorrect.