Tag: alkanoic acids

Questions Related to alkanoic acids

Sodium salt of an organic acid 'X' produces effervescence with conc. $H _2SO _{4}$. 'X' reacts with the acidified aqueous $CaCl _2$ solution to give a white precipitate which decolourises acidic solution of $KMnO _4$. 'X' is 

  1. $C _6H _5COONa$

  2. $HCOONa$

  3. $CH _3COONa$

  4. $Na _2C _2O _4$


Correct Option: D

The trivial name of ${ C } _{ 6 }{ H } _{ 5 }CH=CH-COOH$ is :

  1. cinnamic acid

  2. 1-phenyl-2-carboxy ethane

  3. 3-phenyl prop-2-enoic acid

  4. dihydroxy-3-phenyl propionic acid


Correct Option: A
Explanation:

The trivial name of this compound is Cinnamic acid. Hence, option A is correct.

The correct name of the given compound :
${ CH } _{ 3 }-\overset { \underset { | }{ H }  }{ \underset { \overset { | }{ OH }  }{ C }  } -{ COOH }$

  1. glycoxal

  2. lactic acid

  3. glycine

  4. glyceraldehyde


Correct Option: B
Explanation:

The given compound is Lactic acid.

It contain one $-OH$ group and one $-COOH$ group along with 3 carbon atoms.

IUPAC name of $CH _3CH(CH _3)COOH$ is :

  1. butyric acid

  2. propionic acid

  3. 2-methylpropanoic acid

  4. dimethylacetic acid


Correct Option: C
Explanation:

As it contains 4 carbon and functional group is carboxylic acid so its name is 2-methyl propanoic acid.

Give the condensed formula of following,
$2 - Hydroxy- 1,2,3-propanetricarboxylic$ acid :

  1. $(HOOC)CH _2C(COOH)(OH)CH _2(COOH)$

  2. $(HOOC)CH _2C(COOH)(COOH)CH _2(OH)$

  3. $(HOOC)CH _3C(COOH)CH _2(COOH)$

  4. $(HOOC)CH _2CH _2C(COOH)(OH)CH _2(COOH)$


Correct Option: A
Explanation:
$2 - Hydroxy- 1,2,3-propanetricarboxylic acid$ 
The name suggests functional groups are - three Carboxylic Acid (main) and one Alcohol (secondary) at position C-2, with 3 carbons in main chain. 
The condensed formula is $(HOOC)CH _2C(COOH)(OH)CH _2(COOH)$

Which of the following statements is/are correct?

  1. Methane was named as fire damp as it forms explosive mixture with air

  2. Primary suffixes are added to the root word to show saturation or unsaturation in a C atom

  3. The IUPAC name of valerie acid is pentanoic acid

  4. The common name of hexanoic acid is caproic acid


Correct Option: A,B,C,D
Explanation:
Methane was named as fire damp as it forms explosive mixture with air. It is a flammable gas found in coal mines.
Primary suffix  indicates the degree of saturation or unsaturation in the basic skeleton and is added immediately after the root word.
The IUPAC name of Valeric acid is pentanoic acid  being a liquid of pungent odor obtained from valerian roots.
The common name of hexanoic acid is caproic acid with an odor like limburger cheese.

Aspirin is:

  1. Acetyl salicylic acid

  2. Benzoyl salicylic acid

  3. Chloro benzoic acid

  4. Anthranilic acid


Correct Option: A

Structure of ethanoic acid is:

  1. $\displaystyle { CH } _{ 3 }-{ CH } _{ 2 }-{ CH } _{ 3 }$

  2. $\displaystyle CH _3-\underset {\displaystyle \underset {\displaystyle O}{ ||}}{C}-OH$

  3. $\displaystyle { CH } _{ 3 }-O-{ C } _{ 3 }{ H } _{ 7 }$

  4. $\displaystyle CH _3-\underset {\displaystyle \underset {\displaystyle O}{ ||}}{C}-CH _3$

  5. $\displaystyle CH _3 - CH _2- NH _2$


Correct Option: B
Explanation:

Structure of ethanoic acid is $\displaystyle CH _3-\underset {\displaystyle \underset {\displaystyle O}{ ||}}{C}-OH$. It is also called acetic acid. It can be considered as compound formed by substituting the hydrogen atom of methane with carboxylic group $-COOH$.   

The general formula of carboxylic acids is:

  1. $C _nH _nCOOH$

  2. $C _nH _{2n-1}$

  3. $C _nH _{2n-2}COOH$

  4. $C _nH _{2n+1}COOH$


Correct Option: D
Explanation:
The general formula of carboxylic acid is ${ C } _{ n }{ H } _{ 2n+1 }COOH$
$C{ H } _{ 3 }COOH, { C } _{ 2 }{ H } _{ 5 }COOH$...etc

What is the common name of $CH _2=CHCOOH$?

  1. Anthranilic acid

  2. Citric acid

  3. Acrylic acid

  4. Propenoic acid


Correct Option: C
Explanation:

Common name of $CH _2=CHCOOH$ is acrylic acid.