Chemistry · Physics
Thermodynamics and Chemical Kinetics
1,092 Questions
Thermodynamics and chemical kinetics are crucial branches of physical chemistry. This area focuses on energy transformations, reaction rates, equilibrium constants, and catalysts. These topics carry significant weight in competitive science and engineering examinations.
Enthalpy and energyChemical equilibriumEntropy conceptsReaction kinetics and catalysts
Thermodynamics and Chemical Kinetics Questions
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Intake stroke
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Compression stroke
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Power stroke
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Exhaust stroke
C
Correct answer
Explanation
A spark is produced at the TDC by spark plug, which ignites the compressed air-fuel mixture. This creates an explosion in the combustion chamber. This force gushes the piston towards BDC.
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Tsallis entropy
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Residual entropy
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Negentropy
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Loop entropy
C
Correct answer
Explanation
The negentropy of a living system is the entropy, which consigns to keep its own entropy low. It lies at the junction of entropy and life.
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Vapour pressure of a liquid
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Mass
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Boiling point
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Refractive index
B
Correct answer
Explanation
It tells us about how much of the initial matter was contained in the system and how much will be left after the process is complete. It is an extensive property.
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work is a path function
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temperature affects the heat of reaction
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conservation of mass takes place
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change in enthalpy is a state function
D
Correct answer
Explanation
Change in enthalpy does not depen upon path followed in a reaction. It only depends upon initial & final state of the reaction. So, it is a state function.
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The dual cycle
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The diesel cycle
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The otto cycle
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The Rankine cycle
B
Correct answer
Explanation
The diesel cycle is an illuminated cycle for compressing the ignition engines (ones that don't use a spark plug).
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Isothermal process
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Isobaric process
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Isochoric process
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Adiabatic process
D
Correct answer
Explanation
In this process, no heat is exchanged into or out of a system so, dQ=0. We can control heat flow either by surrounding the system with thermally insulating material or by carrying out the process so promptly that there is not enough time for ascertainable heat flow.
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Hooke's Law
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Hess's Law
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Gauss's law
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Kirchhoff's Law
B
Correct answer
Explanation
Hess's Law states that the heat evolved or absorbed in a chemical process is the same whether the process takes place in one or in several steps.
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By providing optimum temperature
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By lowering activation energy
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By producing ATP
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By raising the temperature
B
Correct answer
Explanation
Enzymes are capable of lowering the activation energy thereby bringing the reactants closer together into its active site allowing the chemical bonds to weaken and thereby leading to the formation of new bonds and thus a new product.
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Friction
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Automatic starter
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Spark plug
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Compression
D
Correct answer
Explanation
Diesel engines use compression ignition - air is compressed to such high pressure and temperature that fuel auto-ignites without spark plugs.
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evolution of heat
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absorption of heat
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both A and B
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None of these
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Small in size
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Variable in shape
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Possess kinetic energy
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Attract each other
B
Correct answer
Explanation
Molecules of a substance are identical in all respects.
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Molecular weight
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Molecular motion
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Molecular shape
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Molecular reactivity
B
Correct answer
Explanation
Physical nature of a chemical substance is determined by its molecular motion.
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Decrease in K.E.
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No effect
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Increase in K.E.
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May increase or decrease in K.E.
C
Correct answer
Explanation
Kinetic energy of molecules increases on heating.
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adiabatic
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isobaric
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isochoric
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isothermal
D
Correct answer
Explanation
An isothermal process is a thermodynamic process where temperature remains constant throughout. 'Iso' means equal or same, and 'thermal' refers to temperature, making 'isothermal' the correct term.
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Endothermic reaction
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Endothermic redox reaction
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Exothermic reaction
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Exothermic redox reaction
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Reduction reaction
B
Correct answer
Explanation
Redox (reduction-oxidation) reactions include all chemical reactions in which atoms have their oxidation state changed.