Chemistry · Physics
Electrochemistry and Current Electricity
224 Questions
Review fundamental concepts of electrochemistry and current electricity through these practice questions. The set includes numerical problems on electrolysis, drift velocity, and electrode potentials. These topics frequently appear in engineering, CSIR NET, and state PSC prelims examinations for thorough preparation.
Electrolysis calculationsElectrode potentialNernst equationDrift velocityFuel cellsMolar conductivity
Electrochemistry and Current Electricity Questions
What is the main component of the positive electrode in a Zinc-Air battery?
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Zinc
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Air
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Manganese dioxide
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Lithium cobalt oxide
B
Correct answer
Explanation
The positive electrode in a Zinc-Air battery is an air electrode, which consists of a porous material that allows oxygen from the air to react with the electrolyte.
What is the main component of the negative electrode in a Zinc-Air battery?
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Zinc
-
Air
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Manganese dioxide
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Lithium cobalt oxide
A
Correct answer
Explanation
The negative electrode in a Zinc-Air battery is a zinc electrode, which consists of a zinc metal anode that undergoes oxidation during discharge.
Which of the following is a disadvantage of electrolysis?
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It produces hydrogen at high purity
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It is a relatively inexpensive process
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It is a renewable source of hydrogen
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It requires a lot of electricity
D
Correct answer
Explanation
Electrolysis requires a lot of electricity, which can be expensive and may come from non-renewable sources.
What is the equation for the Nernst equation?
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E = E° - (RT/nF)lnQ
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E = E° + (RT/nF)lnQ
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E = E° - (nF/RT)lnQ
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E = E° + (nF/RT)lnQ
A
Correct answer
Explanation
The Nernst equation relates the electromotive force of a cell to the concentrations of the reactants and products of the cell reaction.
What are the two main components of a redox flow battery?
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Anode and cathode
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Positive and negative electrodes
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Electrolyte and separator
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Current collector and terminals
C
Correct answer
Explanation
Redox flow batteries consist of two tanks containing electrolyte solutions, separated by a membrane or separator.
What is the typical efficiency range of redox flow batteries?
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60-70%
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70-80%
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80-90%
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90-100%
B
Correct answer
Explanation
Redox flow batteries typically have an efficiency range of 70-80%, meaning that 70-80% of the electrical energy input during charging is recovered during discharging.
What is the typical depth of discharge (DOD) for redox flow batteries?
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20-30%
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50-60%
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70-80%
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90-100%
C
Correct answer
Explanation
Redox flow batteries typically have a DOD of 70-80%, meaning that they can discharge up to 70-80% of their stored energy before needing to be recharged.
What is the Nernst equation, and what does it describe?
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Relates the cell potential to the concentrations of reactants and products
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Relates the cell potential to the temperature and pressure
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Relates the cell potential to the electrode materials
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Relates the cell potential to the current flowing through the cell
A
Correct answer
Explanation
The Nernst equation is a mathematical expression that relates the cell potential of an electrochemical cell to the concentrations of reactants and products involved in the cell reaction.
What is the role of a salt bridge in an electrochemical cell?
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Completes the electrical circuit between the electrodes
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Prevents the mixing of solutions in the half-cells
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Maintains a constant pH in the solutions
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Provides a source of ions for the cell reaction
A
Correct answer
Explanation
The salt bridge in an electrochemical cell completes the electrical circuit between the electrodes, allowing the flow of ions and maintaining electrical neutrality in the cell.
What is the theoretical efficiency limit of a solid state fuel cell?
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80-90%
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50-60%
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20-30%
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10-20%
A
Correct answer
Explanation
Solid state fuel cells have a theoretical efficiency limit of 80-90%, which is higher than conventional combustion engines.
What is the potential energy of a battery?
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$U = mgh$
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$U = rac{1}{2}mv^2$
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$U = rac{1}{2}kx^2$
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$U = -rac{k}{r}$
D
Correct answer
Explanation
The potential energy of a battery is $U = -rac{k}{r}$, where $k$ is a constant and $r$ is the distance between the particles.
In voltammetry, the current is plotted against which of the following?
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Voltage
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Time
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Concentration
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Temperature
A
Correct answer
Explanation
In voltammetry, the current is plotted against the voltage applied to the working electrode.
What is the Nernst equation?
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An equation that relates the electrode potential to the concentration of the analyte.
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An equation that relates the current to the voltage in a potentiometric cell.
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An equation that relates the conductivity of a solution to the concentration of the analyte.
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An equation that relates the mass of an analyte to the current in a coulometric cell.
A
Correct answer
Explanation
The Nernst equation is an equation that relates the electrode potential to the concentration of the analyte.
What is the difference between a potentiometric and a conductometric titration?
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In a potentiometric titration, the equivalence point is determined by measuring the change in electrode potential, while in a conductometric titration, the equivalence point is determined by measuring the change in conductivity.
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Potentiometric titrations are more sensitive than conductometric titrations.
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Conductometric titrations are more versatile than potentiometric titrations.
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All of the above.
D
Correct answer
Explanation
In a potentiometric titration, the equivalence point is determined by measuring the change in electrode potential, while in a conductometric titration, the equivalence point is determined by measuring the change in conductivity. Potentiometric titrations are more sensitive than conductometric titrations. Conductometric titrations are more versatile than potentiometric titrations.