Which Grignard reagent is commercially available?
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Allylmagnesium bromide
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Dimethylmagnesium
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Ethylmagnesium bromide
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Methylmagnesium chloride
D
Correct answer
Explanation
Methylmagnesium chloride is a commercially available Grignard reagent. Like methyllithium, it is the synthetic equivalent to the methyl carbanion synthon. It is usually sold as a solution in tetrahydrofuran. Two molecules of tetrahydrofuran (in the upper part of the drawing) coordinate by their oxygen atoms to magnesium.