On the basis of molecular forces, which one of the following pairs represents elastomers?
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Viton, PVC
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Viton, bromobutyl
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Buna-S, bakelite
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Neoprene, nylon-6,6
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PVC, polythene
A large number of polymer applications in different fields depend on their unique mechanical properties like tensile strength, elasticity, toughness, etc. These mechanical properties are governed by intermolecular forces, e.g., van der Waals forces and hydrogen bonds, present in the polymer. These forces also bind the polymer chains. Under this category, the polymers are classified into the following four sub groups on the basis of magnitude of intermolecular forces present in them- elastomers, fibers, thermoplastic and thermosetting. Elastomers are rubber – like solids with elastic properties. In these elastomeric polymers, the polymer chains are held together by the weakest intermolecular forces. These weak binding forces permit the polymer to be stretched. A few ‘crosslinks’ are introduced in between the chains, which help the polymer to retract to its original position after the force is released, as in vulcanised rubber. Examples are buna-S, buna-N, neoprene, Bromo Isobutylene Isoprene (bromobutyl), Viton (a brand of synthetic rubber and fluoropolymer elastomer commonly used in O-rings and other molded or extruded goods) etc.