Tag: chemistry

Gypsum is mainly used as fertilizer.

When magnesium oxide is dissolved in dilute sulphuric acid, it forms colorless aqueous solution of Magnesium Sulphate. The balanced equation can be written as-
$MgO$ $+$ $H _2SO _4$ $=$ $MgSO _4$ $+$ $H _2O$
This aqueous solution when evaporates and crystallizes, colorless crystals of Epsom salt are obtained.

The two moles of water attached to gypsum is called as "water of hydration".$CaSO _4.2H _2O$

A well powdered phosphate rock or bone ash mixed known quantity of concentrate sulphuric acid is introduced into a cast iron chamber provided with mechanical stirrer and two valves at bottom. Each valve opens in a big chamber called den. The mixture is stirred for 2 to 5 minutes and then dumped mechanically into one of the dens through the valve. The mass is kept in the den for about 24 hours.

${ Ca } _{ 3 }{ \left( P{ O } _{ 4 } \right)  } _{ 2 }+2{ H } _{ 2 }S{ O } _{ 4 }+4{ H } _{ 2 }O\longrightarrow Ca{ ({ H } _{ 2 }P{ O } _{ 4 }) } _{ 2 }+2CaS{ O } _{ 4 }.2{ H } _{ 2 }O+Heat$

A mixture of calcium sulphate and calcium dihydrogen phosphate is obtained .This mixture is called superphosphate.

Single superphosphate (SSP) was the first commercial mineral fertilizer, and it led to the development of the modern plant nutrient industry. This material was once the most commonly used fertilizer, but other phosphorus (P) fertilizers have largely replaced SSP because of its relatively low P content.

The general chemical reaction involved in the production of SSP is

${ Ca } _{ 3 }{ \left( P{ O } _{ 4 } \right)  } _{ 2 }+2{ H } _{ 2 }S{ O } _{ 4 }\longrightarrow Ca{ ({ H } _{ 2 }P{ O } _{ 4 }) } _{ 2 }+2CaS{ O } _{ 4 }$

Monocalcium phosphate is an inorganic compound with the chemical formula $Ca{ ({ H } _{ 2 }P{ O } _{ 4 }) } _{ 2 }$. It is commonly found as the monohydrate $Ca{ ({ H } _{ 2 }P{ O } _{ 4 }) } _{ 2 }.{ H } _{ 2 }O$ Both salts are colourless solids. They are used mainly as superphosphate fertilizers.

A well powdered phosphate rock or bone ash mixed known quantity of concentrate sulphuric acid is introduced into a cast iron chamber provided with mechanical stirrer and two valves at bottom. Each valve opens in a big chamber called den. The mixture is stirred for 2 to 5 minutes and then  dumped mechanically into one of the dens through the valve. The mass is kept in the den for about 24 hours.

A well powdered phosphate rock or bone ash mixed known quantity of concentrate sulphuric acid is introduced into a cast iron chamber provided with mechanical stirrer and two valves at bottom. Each valve opens in a big chamber called den. The mixture is stirred for 2 to 5 minutes and then  dumped mechanically into one of the dens through the valve. The mass is kept in the den for about 24 hours.

A well powdered phosphate rock or bone ash mixed known quantity of concentrate sulphuric acid is introduced into a cast iron chamber provided with mechanical stirrer and two valves at bottom. Each valve opens in a big chamber called den. The mixture is stirred for 2 to 5 minutes and then  dumped mechanically into one of the dens through the valve. The mass is kept in the den for about 24 hours.

A mixture of single superphosphate and triple superphosphate is called double superphosphate. More than 90% of a typical superphosphate fertilizer is water-soluble.

Hence option C is correct.