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Multiple choice pseudo first order reaction order of reactions chemical kinetics electrochemistry and chemical kinetics chemistry

Which of the following is/are correct?

  1. Acid hydrolysis of an ester follows pseudo first order kinetics

  2. Inversion of cane sugar follows pseudo first order kinetics
  3. Decomposition of varous gases on the surface of metallic catalysts, such as decomposition of $HI$ on gold surface also exhibits zero roder kinetics

  4. Radioactivity follows first order kinetics
Reveal answer Fill a bubble to check yourself
A,B,C,D Correct answer
Explanation

 Pseudo first order reaction is a reaction in which concentration of one of the species dominates over the other. Hence the reaction follows the first order kinetics.

Options A, B and C all are the examples of pseudo first order reaction.
Radioactive decay follows first order reaction.

$\mathbf {Hence\ all\ the\ options\ are\ correct.}$

Multiple choice pseudo first order reaction order of reactions chemical kinetics electrochemistry and chemical kinetics chemistry

Nitrosy ligand binds to d-metal atoms in liner and bent fashion and behaves, respectively, as _______________.

  1. $NO^{+}$ and $NO^{+}$
  2. $NO^{+}$ and $NO^{-}$
  3. $NO^{-}$ and $NO^{-}$
  4. $NO^{-}$ and $NO^{+}$
Reveal answer Fill a bubble to check yourself
B Correct answer
Explanation

Linear nitrosyl (NO) ligands act as 3-electron donors (NO+), while bent nitrosyl ligands act as 1-electron donors (NO-).

Multiple choice pseudo first order reaction order of reactions chemical kinetics electrochemistry and chemical kinetics chemistry

Which of the following is pseudo-unimolecular reaction?

  1. $2{ H } _{ 2 }{ O } _{ 2 }\longrightarrow 2{ H } _{ 2 }O+{ O } _{ 2 }$
  2. ${ C } _{ 6 }{ H } _{ 5 }{ N } _{ 2 }Cl+HOH\longrightarrow { C } _{ 6 }{ H } _{ 5 }OH+{ N } _{ 2 }+HCl$
  3. $C{ H } _{ 3 }COO{ C } _{ 2 }{ H } _{ 5 }+NaOH\longrightarrow C{ H } _{ 3 }COONa+{ C } _{ 2 }{ H } _{ 5 }OH$
  4. $2{ O } _{ 3 }\longrightarrow 3{ O } _{ 2 }$
Reveal answer Fill a bubble to check yourself
B Correct answer
Explanation

In a chemical reaction if two or more reactants are involved but the rate of reaction depends only upon the concentration of one of the reactant and independent of other reactants then it is said to be a pseudo unimolecular reaction.

so the option B shows the pseudotype of reaction 

Multiple choice pseudo first order reaction order of reactions chemical kinetics electrochemistry and chemical kinetics chemistry

Rate law for the following reaction; $Ester+H^+\rightleftharpoons Acids+ Alcohol$; is $\frac {dx}{dt}=k [ester]^1 [H^+]^0$. What would be the effect on the rate if concentration of $H^+$ ion is doubled?

  1. Same

  2. Doubled

  3. Half

  4. Data insufficient
Reveal answer Fill a bubble to check yourself
A Correct answer
Explanation

As reaction does not depend on the concentration of $H^+$, therefore, rate will be the same.

Multiple choice pseudo first order reaction order of reactions chemical kinetics electrochemistry and chemical kinetics chemistry

A first-order reaction which is $30\%$ complete in $30$ minutes has a half-life period of:

  1. $24.2\ min$
  2. $58.2\ min$
  3. $102.2\ min$
  4. $120.2\ min$
Reveal answer Fill a bubble to check yourself
B Correct answer
Explanation

It is a 1st order reaction


$k = \dfrac{2.303}{t} log \dfrac{a}{a-x}$

but $k=\dfrac{0.693}{t _{\frac{1}{2}}}$

$\dfrac{0.693}{{t} _{1/2}} = \dfrac{2.303}{30} log \dfrac{100}{70}$

${t} _{1/2} = 58.2 min$

Hence, the correct option is $B$

Multiple choice pseudo first order reaction order of reactions chemical kinetics electrochemistry and chemical kinetics chemistry

In a first order reaction $A \rightarrow B, 60\%$ of the given sample of compounds decomposes in $45$ minutes. The half life of the reaction is ______________.

  1. $12 min$
  2. $34 min$
  3. $40 min$
  4. $43 min$
Reveal answer Fill a bubble to check yourself
B Correct answer
Explanation

For a first order reaction, the rate constant k = (2.303 / t) * log(initial / final). Given 60 percent decomposes in 45 minutes, the remaining fraction is 40 percent (0.4). So k = (2.303 / 45) * log(100 / 40) = (2.303 / 45) * 0.3979 = 0.02036 min^-1. The half life t(1/2) = 0.693 / k = 0.693 / 0.02036 = 34.03 minutes, which rounds to 34 min.

Multiple choice pseudo first order reaction order of reactions chemical kinetics electrochemistry and chemical kinetics chemistry

The acid hydroylsis of ester is:

  1. first order reaction

  2. bimolecular reaction

  3. pseudo unimolecular reaction

  4. none of the above
Reveal answer Fill a bubble to check yourself
A,B,C Correct answer
Explanation

The acid hydrolysis of ester is a first-order reaction, bimolecular reaction and pseudo unimolecular reaction.


When an ester (such as ethyl acetate) is mixed with water it is converted into alcohol and acid according to the following equation: 

$CH _3COOC _2H _5 + H _2O \rightarrow CH _3COOH + C _2H _5OH$

When the amount of water is relatively large, the reaction goes practically to completion (the equilibrium shifts to the right) and the rate is first order with respect to the ester. The hydrolysis takes place slowly with pure water and is catalyzed by acids.

Hence, options A, B and C are correct.

Multiple choice pseudo first order reaction order of reactions chemical kinetics electrochemistry and chemical kinetics chemistry

Inversion of cane-sugar in dilute acid is a:

  1. biomolecuar reaction

  2. pseudo-unimolecular reaction

  3. unimolecular reaction

  4. trimolecular reaction
Reveal answer Fill a bubble to check yourself
B Correct answer
Explanation

The inversion of cane sugar involves water in large excess, making the reaction rate depend only on the sugar concentration, which characterizes it as a pseudo-unimolecular reaction.