Tag: metallic and electrolytic conduction

Quizzes (0) Questions (85)

Questions Related to metallic and electrolytic conduction

Multiple choice metallic and electrolytic conduction electrolysis chemical reactions electrochemistry chemistry

In passing $3\ F$ of electricity through three electrolytic cells connected in series containing $Ag^{\oplus}, Ca^{2+}$, and $Al^{3+}$ ions, respectively. The molar ratio in which the three metal ions are liberated at the electrodes is:

  1. $1 : 2 : 3$
  2. $2 : 3 : 1$
  3. $6 : 3 : 2$
  4. $3 : 4 : 2$
Reveal answer Fill a bubble to check yourself
C Correct answer
Explanation

For all the solution $Q=i\times t$ is same,

${ n } _{ Ag }=\cfrac { Q }{ nF } =\cfrac { Q }{ F } ({ Ag }^{ + }+{ e }^{ - }\longrightarrow Ag)$
${ n } _{ Ca }=\cfrac { Q }{ 2F } ({ Ca }^{ 2+ }+2{ e }^{ - }\rightarrow Ca)$
${ n } _{ Al }=\cfrac { Q }{ 3F } ({ Al }^{ 3+ }+3{ e }^{ - }\rightarrow Al)$
$\therefore $ ${ n } _{ Ag }:{ n } _{ Ca }:{ n } _{ Al }=1:\cfrac { 1 }{ 2 } :\cfrac { 1 }{ 3 } =6:3:2$
$\therefore $   Molar ratio$=6:3:2$.

Multiple choice metallic and electrolytic conduction electrolysis chemical reactions electrochemistry chemistry

Which of the following statement is incorrect with respect to metallic or electronic conductivity ?

  1. Metallic conductivity depends on the number of electrons in the valence shell of an atom of metal

  2. Metallic conductivity depends on the structure of metal and its characteristics

  3. The electrical conductivity of metal increases with increase in temperature

  4. There is no change in the structure of metal during electrical conduction
Reveal answer Fill a bubble to check yourself
C Correct answer
Explanation

Metallic or electronic conductivity is due to the presence of free electrons or/and holes (positive charge). It depends upon:
(i) Number of valence electrons present in the metal 
(ii) Structure and nature (characteristic) of metal 
(iii) Density of metal 
(iv) Temperature 


With increase in temperature, electronic conductivity decreases because the arrangement of electrons gets disturbed. Metallic conductivity does not affect the structure of the metal. 

Multiple choice metallic and electrolytic conduction electrolysis chemical reactions electrochemistry chemistry

At infinite dilution equivalent conductances of $B{ a }^{ +2 }$ & $C{ 1 }^{ - }$ ions are $127$ & $76\ oh{ m }^{ -1 }c{ m }^{ -1 }\ e{ q }^{ -1 }$ respectively. Equivalent conductance of $BaCl _{ 2 }$ at infinite dilution is:

  1. $139.5$
  2. $101.5$
  3. $203$
  4. $279$
Reveal answer Fill a bubble to check yourself
D Correct answer
Explanation

${ \Lambda  } _{ eq }^{ \infty  }\left( { Ba }^{ 2+ } \right) =127{ \Omega  }^{ -1 }{ cm }^{ -1 }{ eq }^{ -1 }\ { \Lambda  } _{ eq }^{ \infty  }\left( { Cl }^{ - } \right) =76{ \Omega  }^{ -1 }{ cm }^{ -1 }{ eq }^{ -1 }\ { \Lambda  } _{ eq }^{ \infty  }\left( { Ba }{ Cl } _{ 2 } \right) ={ \Lambda  } _{ eq }^{ \infty  }\left( { Ba }^{ 2+ } \right) +2{ \Lambda  } _{ eq }^{ \infty  }\left( { Cl }^{ - } \right) \ \qquad \qquad \quad =127+76\times 2\ \qquad \qquad \quad =279{ \Omega  }^{ -1 }{ cm }^{ -1 }{ eq }^{ -1 }$

Multiple choice metallic and electrolytic conduction electrolysis chemical reactions electrochemistry chemistry

When sodium lauryl sulphate is dissolved in water in an appreciable amount, micelle formation takes place. Which of the following options is correct regarding the formation process?

  1. Micelle formation can occur at any temperature

  2. At substantially lower concentrations as concentration increases, conductivity should decrease.

  3. On dilution micelle molar conductance should decrease.

  4. The micelle formation in given case will lead to formation in given case will lead to formation of positively charged colloid.
Reveal answer Fill a bubble to check yourself
B Correct answer
Explanation

At substantially lower concentrations as concentration increases , conductivity increases. Micelle formation can occur at above critical micelle concentration which is at 25$^0$C for sodium lauryl sulphate. It doesnt form a positively charged colloid .

Multiple choice metallic and electrolytic conduction electrolysis chemical reactions electrochemistry chemistry

The charge required for reducing $1$ mole of $MnO^- _4$ to $Mn^{2+}$ is:

  1. $1.93\times 10^5$C
  2. $2.895\times 10^5$C
  3. $4.28\times 10^5$C
  4. $4.825\times 10^5$C
Reveal answer Fill a bubble to check yourself
D Correct answer
Explanation
We will write the reactions and do molar analysis to get clear idea of  the solution.
In the following reaction the oxidation state of Mn is changing from +7 to +2.
$MnO^{-} _{4}+5e^{-}\rightarrow Mn^{2+}$
Here, 5 moles of electrons are needed for reduction of 1 mole of $MnO^{-} _4$ to $ Mn^{2+}$
As, 5 moles of elctrons=5 Faradays
$\implies$Quantity of charge required $=5\times96500=4.825\times10^{5} $ Coulombs

Multiple choice metallic and electrolytic conduction electrolysis chemical reactions electrochemistry chemistry

Fill in the blank with appropriate words.
The electrolytic solution is always neutral because the total charge on $\underline{(i)}$ is equal to $\underline{(ii)}$ on $\underline{(iii)}$. Unlike the metallic conductor, the electrolyte conducts the electric current by virtue of movement of its $\underline{(iv)}$. The property due to which a metal tends to go into solution in term of positive ions is known as $\underline{(v)}$.
(i), (ii), (iii), (iv) and (v) respectively are:

  1. cations, partial charge, anions, electrons, reduction

  2. cations, total charge, anions, ions, oxidation

  3. cations, ionic charge, anions, atoms, dissolution

  4. cations, partial charge, anions, molecules, electrolysis
Reveal answer Fill a bubble to check yourself
B Correct answer
Explanation

To maintain neutrality, the total charge on cation is equal to the total charge on anion.

Metallic conductor contains ions. Hence, the current is due to the movement of ions.
Oxidation is the loss of an electron. 
Hence, metals undergo oxidation.
$M\longrightarrow M^{2+}+2e^-$

Multiple choice metallic and electrolytic conduction electrolysis chemical reactions electrochemistry chemistry

If equivalent conductance of 1M benzoic acid is $12.8\ { ohm }^{ -1 }{ cm }^{ 2 }$ and if the conductance of benzoate ion and ${ H }^{ -1 }$ ion are 42 and $288.42\ { ohm }^{ -1 }{ cm }^{ 2 }$ respectively. Its degree of dissolution is:

  1. 39%

  2. 3.9%

  3. 0.35%

  4. 0.039%
Reveal answer Fill a bubble to check yourself
B Correct answer
Explanation

$\Lambda ^{ 0 } _{ m\left( C _{ 6 }H _{ 5 }COOH \right)  }={ \Lambda  } _{ (C _{ 6 }{ H } _{ 5 }CO{ O }^{ - }) }^{ 0 }\quad +{ \Lambda  }^{ 0 } _{ \left( { H }^{ + } \right)  }$ 

$\ \quad \quad \quad \quad \quad \quad \quad \quad =42+288.42=330.42\ now\quad we\quad have,\ \alpha =\frac { { \Lambda  } _{ m }^{ c } }{ { \Lambda  } _{ m }^{ 0 } } =\frac { 12.8 }{ 330.42 } =3.9$

Multiple choice metallic and electrolytic conduction electrolysis chemical reactions electrochemistry chemistry

Which of the following decreases on dilution of electrolyte solution?

  1. Equivalent conductance

  2. Molar conductance

  3. Specific conductance

  4. Conductance
Reveal answer Fill a bubble to check yourself
B Correct answer
Explanation

Conductance $=\cfrac{kA}{l}$ 

where, $k$ is conductivity
$k=K\times G$
where, $K$ is cell constant
Does not depend on volume of the solution but molar conductance.
$\wedge _m=\cfrac{K}{C}$
$C$ is concentration which depends on volume. Hence, affected by dilution.

Multiple choice metallic and electrolytic conduction electrolysis chemical reactions electrochemistry chemistry

With rise in temperature, electrolytic conductance :

  1. increases

  2. decreases

  3. disappear

  4. none of the above
Reveal answer Fill a bubble to check yourself
A Correct answer
Explanation

Generally the conductivity of a solution increases with temperature, as the mobility of the ions increases.
Conductivity (or specific conductance) of an electrolyte solution is a measure of its ability to conduct electricity.
Electrolytic conductance generally increases with rise in temperature.

Multiple choice metallic and electrolytic conduction electrolysis chemical reactions electrochemistry chemistry

Conductivity of metal decreases with temperature while conductivity of electrolytic conductors  :

  1. increases with temperature

  2. slightly decreases with temperature

  3. remains same

  4. slightly increases with temperature
Reveal answer Fill a bubble to check yourself
A Correct answer
Explanation

In metals, conductivity is due to movement of free electrons. When temperature increases, the vibration of metal ions increases. This results in increase in resistance of metal and hence, decrease in conductivity. In electrolytic conductors, the ions are charge carriers and with increase in temperature, ionization increases and hence, conductivity increases.