Tag: some important compounds of magnesium and calcium

Questions Related to some important compounds of magnesium and calcium

A mixture of slaked lime, sand and water is known as ______.

  1. portland cement

  2. lime mortar

  3. milk of lime

  4. alabaster


Correct Option: A
Explanation:

Portland cement contains calcium oxide (quicklime) and clay (silica along with small quantity of alumina, magnesia and ferric oxide).

Plaster of paris hardens by :

  1. giving $CO _{2}$

  2. changing into carbonate

  3. uniting with water

  4. giving out water


Correct Option: C
Explanation:
$\underset{\text{plaster of paris}}{CaSO _4.1/2H _2O} \xrightarrow[\text{setting}]{H _2O} \underset{\begin{matrix}\text{gypsum}\\\text{othorhombic}\\\text{dihydrate}\end{matrix}}{CaSO _4.2H _2O} \xleftarrow[\text{hardening}]{} \underset{\begin{matrix} \text{gypsum} \\\text{monoclinic dihydrate}\end{matrix}}{CaSO _4.2H _2O}$

Plaster of paris absorbs water to form dihydrate, which sets to form a hard unified mass.

Important constituent of Portland and high alumina cements is?

  1. $Ca _{3}Al _{2}O _{6}$

  2. $CaSiO _{3}$

  3. $CaSO _{4}.2 H _{2}O$

  4. $Fe _{2}CO _{3}$


Correct Option: A
Explanation:

Portland cement essentially consists of compounds of lime(Calcium Oxide CaO) mixed with silica(Silicon dioxide ) and Alumina(Aluminium Oxide).

Plaster of paris in contact with water sets to a hard mass whose composition is :

  1. $CaSO _{4}$

  2. $CaSO _{4}.H _{2}O$

  3. $CaSO _{4}.2H _{2}O$

  4. $CaSO _{4}.Ca(OH) _{2}$


Correct Option: C
Explanation:

On mixing with water, plaster of paris takes up water of crystallization to form orthorhombic calcium sulphate dihydrate. This sets to a hard mass which is monoclinic calcium sulphate dihydrate or gypsum. This is the final product of setting of plaster of paris. Its composition is $CaSO _4 \cdot 2H _2O $.

$B\xleftarrow[]{200^oC} CaSO _4.2H _2O\xrightarrow[]{120^oC}A$
$\downarrow$ Strongly heated          Gypsum
$C$

A, B and C are respectively :
  1. plaster of paris, dead burnt plaster, calcium sulphide

  2. dead burnt plaster, plaster of paris, lime

  3. plaster of paris, dead burnt plaster, lime

  4. anhydrous calcium sulphate, plater of paris, calcium sulphite


Correct Option: C
Explanation:

When calcium sulfate dihydrate is heated to $120^{o} C$, plaster of paris (A) is obtained.
$CaSO _{ 4 }\cdot 2H _{ 2 }O\xrightarrow { 120^o C } CaSO _{ 4 }\cdot \frac { 1 }{ 2 } H _{ 2 }O+\frac { 3 }{ 2 } H _{ 2 }O\ \quad \quad \quad \quad \quad \quad \quad \quad Plaster\quad \quad \quad \quad \quad \ \quad \quad \quad \quad \quad \quad \quad \quad of\ \quad \quad \quad \quad \quad \quad \quad \quad paris\quad  $
When calcium sulfate dihydrate is heated to $200^o C$, anhydrous calcium sulfate is obtained which is known as dead burnt plaster (B).
$CaSO _{ 4 }\cdot 2H _{ 2 }O\xrightarrow { 200^oC } CaSO _{ 4 }+2H _{ 2 }O$
When Dead burnt plaster is strongly heated, lime (C) is obtained.
$CaSO _{ 4 }\xrightarrow { strongly\quad heat } CaO+2SO _{ 3 }$

Cement is mixture of 

  1. Aluminate & Zincate of Calcium

  2. Zincate and Silicate of Calcium

  3. Aluminate and Silicate of Calcium

  4. Aluminate of Calcium and Magnesium


Correct Option: B

Setting of plaster of Paris involves :

  1. The oxidation with atmospheric oxygen

  2. The removal of water to form anhydrous calcium sulfate

  3. The hydration to form the orthorhombic from of gypsum

  4. The reaction with atmospheric carbon dioxide gas


Correct Option: A

The plaster of paris is hardened by 

  1. Liberating ${\text{C}}{{\text{O}} _2}$

  2. Giving out water

  3. Combining with water

  4. Changing into ${\text{CaC}}{{\text{O}} _3}$


Correct Option: C

Setting of plaster of paris is :

  1. oxidation with atmospheric oxygen

  2. combination with atmospheric $CO _2$

  3. dehydration

  4. hydration to yield another hydrate


Correct Option: D
Explanation:

$CaSO _4.1/2H _2O \xrightarrow[setting]{H _2O} CaSO _4.2H _2O \xleftarrow[hardening]{} CaSO _4.2H _2O$

plaster of paris                       gypsum                                gypsum
                                             orthorhombic                monoclinic dihydrate
                                                 dihydrate

The cementation process is:

  1. gel formation

  2. emulsion formation

  3. both of $A$ and $B$

  4. none of the above


Correct Option: A
Explanation:

Cementation process is the hardening of cement during the process of construction. The process starts after adding water to the mixture of cement, sand and small stone pieces. In this, a gel type of product is formed which gets thickened and hardened gradually. So cementation is the process of gel formation.