The main green house gas is
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Ozone
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Oxygen
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Helium
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Cardon dioxide
Greenhouse gases are the gases that contribute to the greenhouse effect by absorbing the earth's heat and re-radiating it towards the earth. Carbon dioxide is the highest (among gases) contributor towards greenhouse effect and contributes about 9-26%, followed by methane (contributes 4-9%), and ozone (3-7%). Over the past few years, carbon dioxide has caused most of the global warming as it is present in abundance in the atmosphere and its amount is increasing over the years. So, even though other gases have a more contributing effect per molecule, the amount of carbon dioxide is so high that it contributes more than the other gases. Due to this carbon dioxide is considered the main greenhouse gas.