Tag: distinguish between black copper oxide and black manganese dioxide

Questions Related to distinguish between black copper oxide and black manganese dioxide

$CuO$ reacts with $HCl$ but $Cu$ does not, why?

  1. Copper has a higher reduction potential than hydrogen, it does not react with non-oxidising acids like $HCl$

  2. Copper has a lower reduction potential than hydrogen, it does not react with non-oxidising acids like $HCl$

  3. Copper is a least reactive metal hence does not react with any acid

  4. Both $Cu$ and $CuO$ does not react with $HCl$


Correct Option: A
Explanation:

Copper does not react with $HCl$ acid, but copper oxide does react. Copper has a higher reduction potential than hydrogen, hence it does not react with non-oxidising acids like $HCl$ or dil.$H _2SO _4$.
But metal oxides are basic substances, and so they generally react with acids forming respective salt and water. 

On reacting copper oxide with hydrochloric acid and filtering it, the filtrate is of which colour?

  1. Blue

  2. Yellow

  3. Black

  4. Brown


Correct Option: A
Explanation:

On reacting copper oxide with $HCl$ and filtering it, copper chloride is formed which is blue in colour.

On adding hydrochloric acid to $MnO _2$, which gas is evolved?

  1. $H _2$

  2. $Cl _2$

  3. $O _2$

  4. None of the above


Correct Option: B
Explanation:

$MnO _2+4HCl \longrightarrow MnCl _2+2H _2O+Cl _2$

Greenish yellow gas chorine is evolved.

Why should the reaction between manganese dioxide and hydrochloric acid carried out in a fume cupboard?

  1. Manganese causes skin irritations

  2. Both reactants and products causes itching

  3. Chlorine gas is poisonous

  4. None of above


Correct Option: C
Explanation:

When manganese dioxide is treated with hydrochloric acid, chlorine gas is released as a product which can be poisonous. Hence, the procedure should take place in a fume cupboard to prevent any harmful effects.

The blue colour filtrate formed after reaction of $HCl$ with $CuO$ is :

  1. $CuCl _2$

  2. $CuCl$

  3. $CuCl _3$

  4. $CuCl _4$


Correct Option: A
Explanation:

The blue coloured filtrate formed after the reaction of $HCl$ with $CuO$ is $CuCl _2$.

When manganese dioxide is treated with HCl, the oxidising agent in the reaction is__________.

  1. $MnO _2$

  2. $HCl$

  3. $H _2O$

  4. The reaction is not a redox reaction


Correct Option: A
Explanation:

When Manganese dioxide reacts with $HCl$, it gives chlorine gas, water and $MnCl _2$. $MnO _2$ is the oxidising agent as it oxidises $HCl$ to $Cl _2$ which loses the hydrogen atom.

On reacting $MnO _2$ with $HCl$,
1. $Mn^{4+}$ is reduced to      
2. $Cl^{-}$ is oxidised to

  1. $Mn^{3+}, Cl^{4+}$

  2. $Mn^{2+}, Cl$

  3. $Mn, Cl$

  4. $Mn$ is not reduced nor $Cl$ is oxidised


Correct Option: B
Explanation:

Manganese dioxide on reacting with hydrochloric acid, undergoes redox reaction. $MnO _2$ is the oxidising agent while $HCl$ is the reducing agent. $Mn^{4+}$ is thus reduced to $Mn^{2+}$ whereas, $Cl^{-}$ is oxidised to $Cl$.

On adding $HCl$ to copper oxide the color of the product is__________.

  1. pink

  2. black

  3. green

  4. white


Correct Option: C
Explanation:

When copper oxide is treated with $HCl$, the products formed $CuCl _2$ and water. The colour of the product formed is bluish green.

On adding $NH _4OH$ to $MnCl _2$, the precipitate formed is :

  1. $NH _4Cl$

  2. $Mn(OH) _2$

  3. no precipitate

  4. both $A$ and $B$


Correct Option: C
Explanation:

No precipitate is formed on reaction of ammonium hydroxide with manganese chloride.

Which acid will react poorly with copper oxide?

  1. $HCl$

  2. $H _2SO _4$

  3. $H _3PO _4$

  4. $H _3PO _2$


Correct Option: C,D
Explanation:

Acids of non metal phosphorous react poorly with copper oxide.

$CuO+2HCl\rightarrow CuCl _2+H _2O$
$CuO+H _2SO _4\rightarrow CuSO _4+H _2O$
so,$H _3PO _4,H _3PO _2$ do not react with copper oxide.