Chemistry
Solid State and Crystal Structures
198 Questions
Solid state chemistry focuses on the structural properties of crystalline solids. Questions cover Bravais lattices, unit cells, and close packed structures. This topic is essential for chemistry papers in UPSC and state PSC examinations.
Bravais lattice typesUnit cell calculationsClose packed structuresCrystal densityBragg's LawWurtzite structure
Solid State and Crystal Structures Questions
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1 and 2
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1, 2 and 3
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3 and 4
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3, 4 and 5
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4 and 5
C
Correct answer
Explanation
Calcium and strontium crystallizes in face centered cubic structure.
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1 and 2
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2 and 3
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3 and 4
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4 and 5
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5 and 6
E
Correct answer
Explanation
Palladium (Pd) and silver (Ag) crystallise in face centred cubic lattice.
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1 and 2
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2 and 3
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3 and 4
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4 and 5
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5 and 6
A
Correct answer
Explanation
Tantalum (Ta) and tungsten (W) crystallises to form body centred cubic lattice.
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Because of high kinetic energy
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Because of strong force of attraction
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Because of high mechanical energy
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Because of indivisibility of its particles
B
Correct answer
Explanation
It is difficult to break an iron nail because of strong force of attraction.
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the space group.
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the lattice constant.
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the crystal lattice.
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unit cell.
A
Correct answer
Explanation
The space group (or crystallographic group, or fedorov group) of a crystal is a description of the symmetry of the crystal, and can be one of 230 types.
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Cubic Crystal system
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Tetragonal Crystal system
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Hexagonal Crystal system
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Orthorhombic Crystal system
C
Correct answer
Explanation
In the hexagonal system, we have an additional axes which gives the crystals six sides. Three of these are equal in length and meet at 60° to each other. The C or vertical axis is at 90° to the shorter axes. Mineralogists sometimes divide this into two systems, the hexagonal and the trigonal, based on their external appearance.
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disclinations.
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edge dislocations.
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point defects.
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srew dislocation.
C
Correct answer
Explanation
Point defects are defects that occur only at or around a single lattice point. They are not extended in space in any dimension. Strict limits for how small a point defect is, are generally not defined explicitly, but typically these defects involve at most a few extra or missing atoms.
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Trigonal crystal system
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Orthorhombic crystal system
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Triclinic crystal system
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Monoclinic crystal system
A
Correct answer
Explanation
The trigonal crystal system is one of the seven crystal systems. It consists of the five point groups of the seven space groups with a rhombohedral lattice. In the classification into 6 crystal families, the trigonal crystal system is combined with the hexagonal crystal system and grouped into a larger hexagonal family.
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Band structure
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Space group
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Lattice parameter
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Crystal habit
B
Correct answer
Explanation
In crystallography, the space group of a crystal is a description of the symmetry of the crystal and can have one of 230 types.
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chromatography.
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crystallography.
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distillation.
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ultrasonography.
B
Correct answer
Explanation
Crystallography is the experimental science of the arrangement of atoms in solids. The word crystallography derives from the Greek words crystallon = cold drop / frozen drop, with its meaning extending to all solids with some degree of transparency, and grapho = write.
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1 and 2
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1 and 3
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2 and 3
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2 and 4
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3 and 4
E
Correct answer
Explanation
Orthorhombic crystal system: Unit cell vector lengths a≠ b ≠ c and unit cell vector angles α = β = γ = 90°
Tetragonal crystal system: Unit cell vector lengths a = b ≠ c and unit cell vector angles α = β = γ = 90°
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Cubic
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Tetragonal
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Orthorhombic
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Rhombohedral
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Monoclinic
C
Correct answer
Explanation
For orthorhombic lattice system, possible Bravais lattices are primitive, body centered, face centered and base centered.
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MgAl2O4 and Mn3O4
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Fe3O4 and Mn3O4
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MgAl2O4 and NiFe2O4
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Fe3O4 and NiFe2O4
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Fe3O4 and Co3O4
D
Correct answer
Explanation
Fe3O4 and NiFe2O4, both are reverse spinels.
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Chain silicates and double chain silicates
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Double chain silicates and sheet silicates
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Sheet silicates and cyclic silicates
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Cyclic silicates and chain silicates
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Cyclic silicates and double sheet silicates
D
Correct answer
Explanation
Both cyclic silicates as well as chain silicates have the same general formula: (SiO3)n2n-
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Cubic : a = b = c and α = β = γ = 90o
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Tetragonal : a = b ≠ c and α = β = γ = 90˚
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Orthorhombic : a ≠ b ≠ c and α = β = γ = 90˚
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Rhombohedral : a = b = c and α = β = γ ≠ 90˚
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Monoclinic : a ≠ b ≠ c and α ≠ β ≠ γ ≠ 90˚
E
Correct answer
Explanation
This option is correct because 'lattice system: edge lengths and axial angles in Monoclinic is a ≠ b ≠ c and α = γ = 90˚, β ≠ 90˚ respectively.
in Triclinic, the 'lattice system: edge lengths and axial angles is a ≠ b ≠ c and α ≠ β ≠ γ ≠ 90˚