Match the following:
| Scientists | Their contribution |
| P. Emerson and Arnold | 1. O2 comes from H2O in photosynthesis |
| Q. Ruben and Kamen | 2. Chloroplasts as the site of photosynthesis |
| R. Arnon | 3. Mechanism of phosphorylation in chloroplast |
| S. Engelmann | 4. Existence of light and dark reaction in photosynthesis |