Questions
Question 1 Multiple Choice (Single Answer)
The branch of thermodynamics that deals with the relationship between heat and other forms of energy in chemical reactions is called:
- Chemical Thermodynamics
- Physical Thermodynamics
- Statistical Thermodynamics
- Quantum Thermodynamics
Question 2 Multiple Choice (Single Answer)
The first law of thermodynamics states that:
- Energy can be created or destroyed.
- Energy can be transferred from one form to another.
- The total amount of energy in the universe is constant.
- All of the above.
Question 3 Multiple Choice (Single Answer)
The second law of thermodynamics states that:
- The entropy of an isolated system always increases.
- The entropy of an isolated system always decreases.
- The entropy of an isolated system remains constant.
- None of the above.
Question 4 Multiple Choice (Single Answer)
The third law of thermodynamics states that:
- The entropy of a perfect crystal at absolute zero is zero.
- The entropy of a perfect crystal at absolute zero is not zero.
- The entropy of a perfect crystal at absolute zero is undefined.
- None of the above.
Question 5 Multiple Choice (Single Answer)
The enthalpy of a system is defined as:
- The total amount of energy in the system.
- The internal energy of the system plus the product of the pressure and volume.
- The difference between the internal energy of the system and the product of the pressure and volume.
- None of the above.
Question 6 Multiple Choice (Single Answer)
The entropy of a system is defined as:
- The measure of the disorder of the system.
- The measure of the energy of the system.
- The measure of the volume of the system.
- None of the above.
Question 7 Multiple Choice (Single Answer)
The Gibbs free energy of a system is defined as:
- The enthalpy of the system minus the product of the temperature and entropy.
- The internal energy of the system minus the product of the temperature and entropy.
- The enthalpy of the system plus the product of the temperature and entropy.
- None of the above.
Question 8 Multiple Choice (Single Answer)
The equilibrium constant for a chemical reaction is defined as:
- The ratio of the concentrations of the reactants to the concentrations of the products.
- The ratio of the partial pressures of the reactants to the partial pressures of the products.
- The ratio of the activities of the reactants to the activities of the products.
- All of the above.
Question 9 Multiple Choice (Single Answer)
The van 't Hoff equation relates:
- The equilibrium constant of a reaction to the temperature.
- The enthalpy of a reaction to the temperature.
- The entropy of a reaction to the temperature.
- The Gibbs free energy of a reaction to the temperature.
Question 10 Multiple Choice (Single Answer)
The Clausius-Clapeyron equation relates:
- The vapor pressure of a liquid to the temperature.
- The boiling point of a liquid to the pressure.
- The freezing point of a liquid to the pressure.
- All of the above.
Question 11 Multiple Choice (Single Answer)
The Trouton's rule states that:
- The entropy of vaporization of a liquid is approximately constant.
- The enthalpy of vaporization of a liquid is approximately constant.
- The Gibbs free energy of vaporization of a liquid is approximately constant.
- None of the above.
Question 12 Multiple Choice (Single Answer)
The Hess's law states that:
- The enthalpy change of a reaction is independent of the path taken.
- The entropy change of a reaction is independent of the path taken.
- The Gibbs free energy change of a reaction is independent of the path taken.
- All of the above.
Question 13 Multiple Choice (Single Answer)
The Le Chatelier's principle states that:
- If a change of condition is applied to a system in equilibrium, the system will shift in a direction that relieves the stress.
- If a change of condition is applied to a system in equilibrium, the system will shift in a direction that increases the stress.
- If a change of condition is applied to a system in equilibrium, the system will not shift.
- None of the above.
Question 14 Multiple Choice (Single Answer)
The third law of thermodynamics is also known as:
- The law of unattainability of absolute zero.
- The law of increasing entropy.
- The law of conservation of energy.
- None of the above.
Question 15 Multiple Choice (Single Answer)
The term 'exergonic' refers to:
- A reaction that releases energy.
- A reaction that absorbs energy.
- A reaction that is in equilibrium.
- None of the above.