Chemical Equilibrium
This quiz covers the fundamental concepts of equilibrium in chemistry.
Questions
What is the state of a system in which the concentrations of reactants and products do not change over time?
- Equilibrium
- Non-equilibrium
- Dynamic equilibrium
- Steady state
Which of the following factors can shift the equilibrium position of a reaction?
- Temperature
- Pressure
- Concentration of reactants
- All of the above
What is the relationship between the equilibrium constant (K) and the concentrations of reactants and products at equilibrium?
- K = [products]/[reactants]
- K = [reactants]/[products]
- K = [products]^2/[reactants]^2
- K = [reactants]^2/[products]^2
What is the relationship between the standard free energy change (ΔG°) and the equilibrium constant (K)?
- ΔG° = -RTlnK
- ΔG° = RTlnK
- ΔG° = -RTK
- ΔG° = RTK
Which of the following reactions is an example of a homogeneous equilibrium?
- CaCO3(s) <=> CaO(s) + CO2(g)
- H2(g) + Cl2(g) <=> 2HCl(g)
- Fe(s) + CuSO4(aq) <=> FeSO4(aq) + Cu(s)
- CH3COOH(aq) + H2O(l) <=> CH3COO-(aq) + H3O+(aq)
Which of the following reactions is an example of a heterogeneous equilibrium?
- CaCO3(s) <=> CaO(s) + CO2(g)
- H2(g) + Cl2(g) <=> 2HCl(g)
- Fe(s) + CuSO4(aq) <=> FeSO4(aq) + Cu(s)
- CH3COOH(aq) + H2O(l) <=> CH3COO-(aq) + H3O+(aq)
What is the effect of increasing temperature on the equilibrium position of an exothermic reaction?
- The equilibrium position shifts to the left.
- The equilibrium position shifts to the right.
- The equilibrium position does not change.
- The equilibrium position cannot be determined.
What is the effect of increasing temperature on the equilibrium position of an endothermic reaction?
- The equilibrium position shifts to the left.
- The equilibrium position shifts to the right.
- The equilibrium position does not change.
- The equilibrium position cannot be determined.
What is the effect of increasing pressure on the equilibrium position of a reaction in which the number of moles of gas on the product side is greater than the number of moles of gas on the reactant side?
- The equilibrium position shifts to the left.
- The equilibrium position shifts to the right.
- The equilibrium position does not change.
- The equilibrium position cannot be determined.
What is the effect of increasing pressure on the equilibrium position of a reaction in which the number of moles of gas on the product side is less than the number of moles of gas on the reactant side?
- The equilibrium position shifts to the left.
- The equilibrium position shifts to the right.
- The equilibrium position does not change.
- The equilibrium position cannot be determined.
Which of the following is a common ion effect?
- The addition of a salt containing a common ion to a solution decreases the solubility of a sparingly soluble salt.
- The addition of a salt containing a common ion to a solution increases the solubility of a sparingly soluble salt.
- The addition of a salt containing a common ion to a solution has no effect on the solubility of a sparingly soluble salt.
- The addition of a salt containing a common ion to a solution can either increase or decrease the solubility of a sparingly soluble salt, depending on the specific salt.
Which of the following is a buffer solution?
- A solution that contains a weak acid and its conjugate base.
- A solution that contains a weak base and its conjugate acid.
- A solution that contains both a weak acid and a weak base.
- A solution that contains a salt of a weak acid and a strong base.
What is the pH of a buffer solution?
- The pH of a buffer solution is equal to the pKa of the weak acid.
- The pH of a buffer solution is equal to the pKb of the weak base.
- The pH of a buffer solution is equal to the average of the pKa and pKb of the weak acid and weak base.
- The pH of a buffer solution can be calculated using the Henderson-Hasselbalch equation.
What is the role of a catalyst in an equilibrium reaction?
- A catalyst increases the rate of the forward reaction.
- A catalyst increases the rate of the reverse reaction.
- A catalyst increases the rate of both the forward and reverse reactions.
- A catalyst does not affect the rate of the reaction.