Chemical properties of diazonium salts - class-XII

Chemical properties of diazonium salts

9 Questions Published

Questions

Question 1 Multiple Choice (Single Answer)

Sandmeyer reaction is better than Gattermann reaction because:

  1. sandmeyer reaction uses salt of copper while Gattermann reaction uses copper powder.
  2. only one salt is produced in Sandmeyer reaction while Gattermann reaction produces two salts.
  3. sandmeyer reaction gives better yield than Gattermann reaction.
  4. all of the above.
Question 2 Multiple Choice (Single Answer)

Which of the reaction would you choose for the most beneficial conversion shown below?
$ArN _2^+X \rightarrow ArCl$

  1. Sandmeyer Reaction
  2. Gattermann Reaction
  3. Directly reacting with $HCl$
  4. Both A and B
Question 3 Multiple Choice (Single Answer)

Replacement of diazonium group of fluorine is known as:

  1. Gattermann reaction
  2. Sandmeyer reaction
  3. Balz-Schiemann reaction
  4. Etard reaction
Question 4 Multiple Choice (Single Answer)

3- Amino-2, 3-dimethyl butan-2-ol when treated with $ NaNO _{2}/HCl$ gives product (X). (X) on treatment with $LiAlH _{4}$ forms (Y). (Y) on heating with $conc. H _{2}SO _{4}$ forms (Z). The molecular weight of (Z) is :

  1. 81
  2. 82
  3. 83
  4. 84
Question 5 Multiple Choice (Single Answer)

Shweta found her pet's cloth discoloured and decided to renovate the dress by colouring it. Which of the following solution of compound should she choose to do so?

  1. Ammonia
  2. Ester
  3. Diazonium salts
  4. Aldehyde
Question 6 Multiple Choice (Single Answer)

Which of the following compound should we choose with Aryldiazonium salt to produce Azo dyes?

  1. Phenol
  2. Arylamines
  3. Both A and B
  4. Diazonium salt is already coloured
Question 7 Multiple Choice (Single Answer)

When diazonium salt solution is treated with water at a temperature of 283 K it forms:

  1. ester
  2. alcohol
  3. amines
  4. phenol
Question 8 Multiple Choice (Single Answer)

Which of the following is correct method to convert p-toluidine to p-toluic acid?

  1. $ Diazotisation, \, CuCN, \, H _2/Pd$
  2. $CHCl _3/NaOH,\, KCN, \, Sn/HCl$
  3. $ Diazotisation, \, CuCN/KCN, H _2O/H^+$
  4. $ Diazotisation, \, NaCN, \, NaOH$