Questions
What is the lowest energy of the spectral line emitted by the hydrogen atom in the Lyman series? (h=Plank constant; C=Velocity of light; R=Rydberg constant)
- $\dfrac{5hcR}{36}$
- $\dfrac{4hcR}{3}$
- $\dfrac{3hcR}{4}$
- $\dfrac{7hcR}{144}$
The ratio of the wave numbers of the radiation corresponding to the third line of Balmer series and the second line of the Paschen series of hydrogen spectrum is:
- 21/16 x 9/4
- 25/16 x 9/4
- 21/25 x 9/4
- 16/25 x 9/4
What are the values of $n _{1}$ and $n _{2}$ respectively for $H _{\beta}$ line in the Lyman series of hydrogen atomic spectrum?
- 3 and 5
- 2 and 3
- 1 and 3
- 2 and 4
The first emission line of hydrogen atomic spectrum in the Balmer series appears at (R = Rydberg constant):
- $\frac{5R}{36}cm^{-1}$
- $\frac{3R}{4}cm^{-1}$
- $\frac{7R}{144}cm^{-1}$
- $\frac{9R}{400}cm^{-1}$
The spectrum of helium is expected to be similar to that of:
- $H$
- $Li^+$
- $Na$
- $He^+$
The distance between 3rd and 2nd orbits in the hydrogen atom is:
- $2.646\times {10}^{-8}cm$
- $2.116\times {10}^{-8}cm$
- $1.058\times {10}^{-8}cm$
- $2.646\times {10}^{-10}cm$
The energy of second Bohr orbit of the hydrogen atom is $-328kJ$ ${mol}^{-1}$. Hence the energy of fourth Bohr orbit would be:
- $-41kJ$ ${mol}^{-1}$
- $-13121kJ$ ${mol}^{-1}$
- $-164kJ$ ${mol}^{-1}$
- $-82kJ$ ${mol}^{-1}$
The shortest $\lambda$ for the Lyman series of hydrogen atom is:
- $911.7A^o$
- $700 A^o$
- $600 A^o$
- $811 A^o$
The first emission line in the atomic spectrum of hydrogen in the Balmer Series appears at:
- $\dfrac {9R _H}{400}cm^{-1}$
- $\dfrac {7R _H}{144}cm^{-1}$
- $\dfrac {3R _H}{4}cm^{-1}$
- $\dfrac {5R _H}{36}cm^{-1}$
Statement I : Wavelength of limiting line of lyman series is less than wavelength of limiting line of Balmer series.
Statement II: Rydberg constant value is same for all elements
- Statement I is true, Statement II is also true; Statement is the correct explanation of Statement I
- Statement I is true, Statement II is also true; Statement II is not the correct explanation of Statement I
- Statement I is true, Statement II is false
- Statement I is false, Statement II is true
Which are correct for emission spectra of Balmer series in $H$-atom?
- $\displaystyle\lambda _{(in nm)}=364.56\left[\frac{n^2 _2}{n^2 _2-n^2 _1}\right]$; where $n _1=2$ and $n _2 > 2$
- $\dfrac{1}{\lambda}=R\left[\displaystyle\frac{1}{n^2 _1}-\frac{1}{n^2 _2}\right];$ where $n _1=2$ and $n _2 > 2$; $R=3.29\times 10^{15}H _z$
- $\displaystyle\frac{1}{\lambda}=R _H \left[ \frac{1}{n^2 _1}-\frac{1}{n^2 _2}\right ];$ where $n _1=2$ and $n _2 > 2$; $R _H=1.09737\times 10^5cm^{-1}$
- $\dfrac{1}{\lambda}=\frac{4c(in msec^{-1})}{364.56\times 10^{-9}}\left[\frac{1}{n^2 _1}-\frac{1}{n^2 _2}\right];$ where $n _1=2$ and $n _2 > 2$;
$c$ is speed of light.
In which transition one quantum of energy is emitted?
- $\displaystyle n=4\rightarrow n=2$
- $\displaystyle n=3\rightarrow n=1$
- $\displaystyle n=4\rightarrow n=1$
- All of them
An $e^{-}$ of $He^{+}$ makes a transition and emits $6^{th}$ line of Balmer series. Similar wavelength of radiation is absorbed by hydrogen like specie to give $9^{th}$ line of paschen series in its spectrum. The value of Z of the hydrogen like specie is :
- 1
- 2
- 3
- 4
- 5
- 2
- 3
- 4
The emission spectrum of hydrogen is found to satisfy the expression for the energy change $\triangle E$ (in joules) such that $\triangle E = 2.18\times 18^{-18}(\frac{1}{n _1^2}-\frac{1}{n _2^2})J$ where $n _1$= 1, 2, 3, .......and $n _2$ = 2, 3, 4. The spectral lines corresponds to Paschen series if :
- $n _1 = 1$ and $ n _2 = 2, 3, 4$
- $n _1 = 3$ and $ n _2 = 4, 5, 6$
- $n _1 = 1$ and $ n _2 = 3, 4, 5$
- $n _1 = 2$ and $ n _2 = 3, 4, 5$
What would be the wavelength and name of series respectively for the emission transition for H-atom if it starts from the orbit having radius 1.3225 nm and ends at 211.6 pm?
- 434 nm, Balmer
- 434 pm, Paschen
- 545 pm, Pfund
- 600 nm, Lyman