Solid State Chemistry - Point Defects and Interstitial Compounds

Questions about F-centres (color centers), point defects in crystals, and properties of interstitial compounds in solid state chemistry

13 Questions Published

Questions

Question 1 Multiple Choice (Single Answer)

The anionic sites occupied by unpaired electrons are called F-centers or colour centers. They impart ______ $(X)$ colour to the crystals on $NaCl.$ Excess of lithium makes $LiCl$ crystals ______ $(Y)$ and excess of potassium makes $KCl$ crystals ______ $(Z)$. $(X)$, $(Y)$ and $(Z)$ are:

  1. yellow, green and pink respectively.
  2. pink, yellow and violet (or lilac) respectively.
  3. yellow, pink and violet (or lilac) respectively.
  4. red, yellow and pink respectively,
Question 2 Multiple Choice (Single Answer)

$F-$centres are :

  1. the electrons trapped in anionic vacancies
  2. the electron trapped in cationic vacancies
  3. non-equivalent sites of stoichiometric compound
  4. All of the above
Question 3 Multiple Choice (Single Answer)

The incorrect statement is :

  1. When crystals of NaCI are heated in an atmosphere of sodium vapour, it appears yellow due to F-centres.
  2. $ O _2 $ is paramagnetic , $ CrO _2 $ is Ferromagnetic and $ MnO $ is anti-Ferromagnetic
  3. Certain oxides $ VO, VO _2VO _3 $ and $ TiO _3 $ show metallic properties at all temperatures.
  4. CCP & HCP have same coordination number.
Question 4 Multiple Choice (Single Answer)

The correct statement regarding $F-$centre is:

  1. electron are held in the voids of crystals
  2. $F-$centre produces colour to the crystals
  3. conductivity of the crystal increases due to $F-$centre
  4. all of the above
Question 5 Multiple Choice (Single Answer)

The presence of excess sodium in sodium chloride makes the crystal appearance yellow. This is due to the presence of

  1. Schottky defect
  2. Frenkel defect
  3. F-centres
  4. Interstitial defects
Question 6 Multiple Choice (Single Answer)

Each of the following statement is correct except

  1. the lattice positions left vacant by anion and occupied by electrons are called F-centres
  2. the presence of F-centres makes the lattice electrically neutral and diamagnetic
  3. the presence of F-centres gives colour to the crystals
  4. F-centres contain unpaired electrons
Question 7 Multiple Choice (Single Answer)

In feldspar and zeolite, $Si^{4+}$ ions are replaced by which ions?

  1. Oxide ion
  2. Hydroxide ion
  3. Aluminium ion
  4. Potassium ion
Question 8 Multiple Choice (Single Answer)

ZnO shows yellow colour on Heating due to:

  1. d-d transition
  2. C-T spectra
  3. Higher polarisation caused by $Zn^{2+}$ ion
  4. F-centres
Question 9 Multiple Choice (Single Answer)

Interstitial compounds are formed when small atoms are trapped inside the crystal lattice of
metals. Which of the following is not the characteristic property of interstitial compounds?

  1. They have high melting points in comparison to pure metals.
  2. They are very hard.
  3. They retain metallic conductivity.
  4. They are chemically very reactive.
Question 10 Multiple Choice (Single Answer)

Which of the following is an interstital compound ?

  1. $ PdCI _2 $
  2. $ NH _3 $
  3. $ ZnO$
  4. $ TiH $
Question 11 Multiple Choice (Single Answer)

Which of the following is incorrect about interstitial compounds?

  1. Very reactive
  2. High metallic conductivity
  3. Very hard
  4. High melting point
Question 12 Multiple Choice (Single Answer)

Which forms interstitial compounds?

  1. $Fe$
  2. $Co$
  3. $Ni$
  4. All
Question 13 Multiple Choice (Multiple Answers)

Addition of non-metals like B and C to the interstitial sites of a transition metal results the metal :

  1. of more ductability
  2. of less ductability
  3. Less malleable
  4. of more hardness