Solid State Chemistry - Point Defects and Interstitial Compounds
Questions about F-centres (color centers), point defects in crystals, and properties of interstitial compounds in solid state chemistry
Questions
The anionic sites occupied by unpaired electrons are called F-centers or colour centers. They impart ______ $(X)$ colour to the crystals on $NaCl.$ Excess of lithium makes $LiCl$ crystals ______ $(Y)$ and excess of potassium makes $KCl$ crystals ______ $(Z)$. $(X)$, $(Y)$ and $(Z)$ are:
- yellow, green and pink respectively.
- pink, yellow and violet (or lilac) respectively.
- yellow, pink and violet (or lilac) respectively.
- red, yellow and pink respectively,
$F-$centres are :
- the electrons trapped in anionic vacancies
- the electron trapped in cationic vacancies
- non-equivalent sites of stoichiometric compound
- All of the above
The incorrect statement is :
- When crystals of NaCI are heated in an atmosphere of sodium vapour, it appears yellow due to F-centres.
- $ O _2 $ is paramagnetic , $ CrO _2 $ is Ferromagnetic and $ MnO $ is anti-Ferromagnetic
- Certain oxides $ VO, VO _2VO _3 $ and $ TiO _3 $ show metallic properties at all temperatures.
- CCP & HCP have same coordination number.
The correct statement regarding $F-$centre is:
- electron are held in the voids of crystals
- $F-$centre produces colour to the crystals
- conductivity of the crystal increases due to $F-$centre
- all of the above
The presence of excess sodium in sodium chloride makes the crystal appearance yellow. This is due to the presence of
- Schottky defect
- Frenkel defect
- F-centres
- Interstitial defects
Each of the following statement is correct except
- the lattice positions left vacant by anion and occupied by electrons are called F-centres
- the presence of F-centres makes the lattice electrically neutral and diamagnetic
- the presence of F-centres gives colour to the crystals
- F-centres contain unpaired electrons
In feldspar and zeolite, $Si^{4+}$ ions are replaced by which ions?
- Oxide ion
- Hydroxide ion
- Aluminium ion
- Potassium ion
ZnO shows yellow colour on Heating due to:
- d-d transition
- C-T spectra
- Higher polarisation caused by $Zn^{2+}$ ion
- F-centres
Interstitial compounds are formed when small atoms are trapped inside the crystal lattice of
metals. Which of the following is not the characteristic property of interstitial compounds?
- They have high melting points in comparison to pure metals.
- They are very hard.
- They retain metallic conductivity.
- They are chemically very reactive.
Which of the following is an interstital compound ?
- $ PdCI _2 $
- $ NH _3 $
- $ ZnO$
- $ TiH $
Which of the following is incorrect about interstitial compounds?
- Very reactive
- High metallic conductivity
- Very hard
- High melting point
Which forms interstitial compounds?
- $Fe$
- $Co$
- $Ni$
- All
Addition of non-metals like B and C to the interstitial sites of a transition metal results the metal :
- of more ductability
- of less ductability
- Less malleable
- of more hardness