Chemical Bonding
Tests molecular geometry and VSEPR theory concepts including lone pairs, hybridization, and shapes of molecules and ions
Questions
Which of the following molecules/ions has the maximum number of lone pairs?
- XeF2
- CO2
- XeF5-
- ClF3
- TiCl4
Which of the following pairs is not correctly matched?
- XeF4 - tetrahedral
- SF4 - seesaw
- Wl6 - octahedral
- BrF3 - T-shaped
- XeOF4 - square pyramidal
Which of the following molecules/ions possess bent geometry?
- I3-
- XeF2
- H2O
- SO2
- Only (1) and (2)
- Only (2) and (3)
- Only (3) and (4)
- (1), (2) and (3)
- (2), (3) and (4)
Which of the following molecules bears no lone pair of electrons with linear shape?
- XeF2
- CCl2
- CdI2
- XeF4
- PbCl2
Which of the following molecules bears one lone pair on the central atom with bent shape?
- SO2
- F2O
- H2O
- XeF2
- O3
Which of the following pairs are incorrectly matched?
P. NH3 - Trigonal planar
Q. SO3 - Trigonal planar
R. XeCl2 - Linear geometry
S. XeF5- - Trigonal bipyramidal
- (P) and (Q)
- (Q) and (R)
- (R) and (S)
- (P) and (R)
- (P) and (S)
Which of the following statements is/are incorrect?
(P) Both XeF2 and OF2 molecules are identical in bond pairs and lone pairs, but are different in their shapes.
(Q) NO3-, BF3 and SO3 possess identical geometry.
(R) The bond angle in formaldehyde (H-C=O) is greater than that in ethylene (H-C=C).
- Only (P)
- Only (Q)
- Only (R)
- Both (P) and (Q)
- Both (Q) and (R)
Match the following:
| Column - I |
</strong>|<strong>Column - II </strong>|
|A. WBr2F4|1. Seesaw|
|B. TeF4|2. Octahedral|
|C. XeO4|3. Tetrahedral|
|D. XeOF5-|4. Pentagonal pyramidal|
| |5. Square planar|
- A - 2, B - 1, C - 3, D - 4
- A - 2, B - 4, C - 1, D - 5
- A - 5, B - 3, C - 5, D - 4
- A - 4, B - 1, C - 3, D - 2
- A - 2, B - 5, C - 4, D - 3
Which of the following statements is/are false?
P. IF8- has a square antiprismatic shape.
Q. IF7 bears zero lone pairs of electrons and possesses pentagonal bipyramidal geometry.
R. SnCl2 has one lone pair of electrons and a linear shape.
S. IOF3 has seesaw geometry.
- Only (P)
- Both (P) and (Q)
- Both (Q) and (R)
- Both (R) and (S)
- Only (R)
Which of the following pairs has square planar geometry?
- SCl2, XeF2
- SnBr2, SeF2
- SCl4, CH4
- XeF4, ICl4-
- TiCl4, XeO4
The geometry of carboplatin is
- linear
- trigonal planar
- tetrahedral
- square planar
- octahedral
How many sigma and pi bonds does calcium carbide have?
- One sigma and one pi
- Two sigma and one pi
- One sigma and two pi
- Two sigma and two pi
- Three sigma and two pi
Which of the following sets of atomic orbitals represent(s) the formation of a square planar complex?
- s, px, py, pz
- s, px, py, pz, d
- s, px, py, pz, d, d
- d, s, px, py
- Both (3) and (4)
Match the following:
| Group - I (molecules/ions) |
</strong>|<strong> Group - II (corresponding shapes) </strong>|
|P. BrF3|1. Pyramidal|
|Q. XeOF5-|2. Bent|
|R. SeO32-|3. T-shaped|
|S. Cl2O|4. Pentagonal pyramidal|
| |5. Trigonal planar|
- P - 3, Q - 4, R - 1, S - 2
- P - 2, Q - 4, R - 1, S - 5
- P - 5, Q - 1, R - 4, S - 2
- P - 2, Q - 3, R - 1, S - 4
- P - 2, Q - 3, R - 5, S - 1
Match the following:
| List - A |
</strong>|<strong>List - B
</strong>|<strong> List - C </strong>|
|P. IOF52-|1. Square planar|i. 1|
|Q. XeCl2|2. Pentagonal pyramidal|ii. 2|
|R. SbI5|3. Linear|iii. 0|
|S. BrF4-|4. Trigonal bipyramidal|iv. 3|
- P - 3 - i, Q - 2 - iv, R - 4 - iii, S - 1 - ii
- P - 2 - i, Q - 3 - iv, R - 1 - iii, S - 4 - ii
- P - 2 - i, Q - 3 - ii, R - 1 - iii, S - 4 - iv
- P - 2 - i, Q - 3 - iv, R - 1 - ii, S - 4 - iii
- P - 2 - i, Q - 3 - iv, R - 4 - iii, S - 1 - ii