Inorganic Chemistry (GATE)
Periodic trends, chemical bonding, crystal structures, and properties of elements and compounds for engineering entrance exams
Questions
Which of the following statements are not correct about boron?
- Boron halides do not form dimers.
- Boron is a bad conductor of electricity.
- Boron exists in amorphous form only.
- The hydroxides and oxides of boron are amphoteric.
- The melting and boiling point of boron are lower than that of aluminium.
- Boron forms only covalent compounds.
- 1, 2 and 3
- 1, 4 and 6
- 2, 3 and 4
- 3, 4 and 5
- 3, 5 and 6
Which among the following statements is/are correct?
- All the noble gases, except radon, occur in the atmosphere.
- XePtF6 was the first noble gas compound.
- XeF2 has bent geometry.
- Noble gases have large positive values of electron gain enthalpy.
- 1 and 3
- 1, 2 and 4
- 1, 2, 3 and 4
- 2 and 3
- 2, 3 and 4
Which of the following are examples of tribasic acid?
- Metaphosphoric acid
- Pyrophosphoric acid
- Orthophosphoric acid
- Orthophosphorous acid
- Hypophosphorous acid
- Hypophosphoric acid
- Peroxyphosphoric acid
- 1 and 3
- 2 and 5
- 3 and 7
- 4 and 6
- 5 and 7
Which of the following statements regarding phosphine are incorrect?
- It is a trigonal pyramidal molecule.
- Point group of phosphine is C2v.
- The length of the P-H bond is 1.42 Å.
- The H-P-H bond angles are 109.5°.
- It is a polar molecule.
- 1 and 2
- 1 and 5
- 2 and 3
- 2 and 4
- 3 and 4
Identify the incorrect statements.
- HI has lower boiling point than HCl.
- UF6 is more covalent than UF4.
- All halogens can exhibit positive oxidation states.
- Bleaching action of chlorine is due to oxidation.
- 1 and 2
- 1 and 3
- 1 and 4
- 2 and 3
- 2 and 4
Which of the following alkaline earth metals crystallise in face centered cubic structure?
- Beryllium
- Magnesium
- Calcium
- Strontium
- Barium
- 1 and 2
- 1, 2 and 3
- 3 and 4
- 3, 4 and 5
- 4 and 5
Which of the following statements are correct about halogens?
- Fluorine is a stronger oxidising agent than chlorine.
- Halogens have maximum negative electron gain enthalpy in the corresponding periods.
- The negative electron gain enthalpy of fluorine is more than that of chlorine.
- The enthalpy of dissociation of F2 is more than Cl2.
- 1 and 2
- 1 and 4
- 2 and 3
- 2 and 4
- 3 and 4
Which of the following second row transition metals crystallise in face centred cubic lattice?
- Nb
- Mo
- Tc
- Ru
- Pd
- Ag
- 1 and 2
- 2 and 3
- 3 and 4
- 4 and 5
- 5 and 6
Which of the following statements are not true?
- Sulphates and hydroxides of alkali metals are more soluble than those of alkali metals.
- Solubility of alkaline earth metal sulphates increases down the group.
- Solubility of alkaline earth metal hydroxides decreases down the group.
- Alkaline earth metal ions have greater hydration enthalpies than alkali metal ions.
- 1 and 2
- 1 and 3
- 2 and 3
- 2 and 4
- 3 and 4
Which of the following third row transition metals crystallise to form body centred cubic lattice?
- Tantalum
- Tungsten
- Rhenium
- Osmium
- Platinum
- Gold
- 1 and 2
- 2 and 3
- 3 and 4
- 4 and 5
- 5 and 6
Identify the incorrect statements.
- Alkaline earth metals have stronger metallic bonding than the corresponding alkali metals.
- Alkaline earth metals have higher densities than corresponding alkali metals.
- Melting points in alkaline earth metals are lower than for the corresponding alkali metals.
- Alkaline earth metal carbonates higher thermal stability than corresponding alkali metal carbonates.
- 1 and 2
- 1 and 4
- 2 and 3
- 2 and 4
- 3 and 4
Directions: In the question given below, there are two statements labelled as Assertion (A) and Reason (R). Mark your answer as per the codes provided below:
Assertion: NF3 has dipole moment but, BF3 has not.
Reason: If the molecule is unsymmetrical, the resultant dipole moment of the molecule is not zero.
- Both A and R are true and R is the correct explanation of A.
- Both A and R are true but R is not the correct explanation of A.
- A is true but R is false
- A is false but R is true.
- Both A and R are false.
For which following properties Li has higher value than Na?
- Hydration enthalpy
- Thermal stability of hydride
- Stability of carbonate
- Basic character of hydroxide
- 1 and 2
- 1 and 3
- 1 and 4
- 2 and 3
- 3 and 4