Kilowatt (kW) is the odd one out because it's a unit of POWER (rate of energy use), while joule, calorie, and kilowatt-hour are all units of ENERGY or work done. Power = Energy / Time, so 1 kW = 1 kJ/s. The kilowatt-hour (kWh) is a unit of energy equal to 1 kW used for 1 hour.