To answer this question, let's go through each option to understand why it is correct or incorrect:
Option A) It is one of the largest and most populated cities in the world - This option is correct. Mexico City is indeed one of the largest and most populated cities in the world.
Option B) It houses the Metropolitan Cathedral, the largest and oldest cathedral in North and South America - This option is correct. Mexico City is home to the Metropolitan Cathedral, which is indeed the largest and oldest cathedral in North and South America.
Option C) Teotihuacan, an important archaeological site is situated close to it - This option is correct. Teotihuacan, an important archaeological site, is indeed located close to Mexico City.
Option D) South America’s largest zoo is located here - This option is incorrect. Mexico City is not located in South America, so it cannot have South America's largest zoo.
Therefore, the correct answer is D) South America’s largest zoo is located here. This option is incorrect because Mexico City is not located in South America, so it cannot have South America's largest zoo.