Multiple choice

If M is molecular wt of the ion IO4-, what is the equivalent mass if it is converted into I2 in acidic medium?

  1. <span style="font-size:11.0pt;line-height:115%;font-family:"Calibri","sans-serif";mso-ascii-theme-font:minor-latin;mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin;mso-ansi-language:EN-US;mso-fareast-language:EN-US;mso-bidi-language:AR-SA">M/6

  2. <span style="font-size:11.0pt;line-height:115%;font-family:"Calibri","sans-serif";mso-ascii-theme-font:minor-latin;mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin;mso-ansi-language:EN-US;mso-fareast-language:EN-US;mso-bidi-language:AR-SA">M/7

  3. <span style="font-size:11.0pt;line-height:115%;font-family:"Calibri","sans-serif";mso-ascii-theme-font:minor-latin;mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin;mso-ansi-language:EN-US;mso-fareast-language:EN-US;mso-bidi-language:AR-SA">M/5

  4. <span style="font-size:11.0pt;line-height:115%;font-family:"Calibri","sans-serif";mso-ascii-theme-font:minor-latin;mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin;mso-ansi-language:EN-US;mso-fareast-language:EN-US;mso-bidi-language:AR-SA">M
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B Correct answer
Explanation

For conversion of IO4- to I2 in acidic medium the reaction is as under. IO4- + 7e- → I2……………… here oxidation state of I in IO4- is +7 and in I2 is 0, so gain in number of electrons is of +7. We know that equilibrium weight is given by eqilibrium weight = molecular mass/gain in number of electrons = M/7

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