Which of the following ions have identical geometry?
(i) NH4+, (ii) IF4+, (iii) ClO2-, (iv) ClO4
-
Only i and ii.
-
ii and iii.
-
Only i and iv
-
Only i, ii and iii.
-
Only ii, iii and iv.
C
Correct answer
Explanation
NH4+ and ClO4- both ions have four bond pairs of electrons and zero lone pairs of electrons with tetrahedral geometry. IF4+ has four bond pairs of electrons and one lone pair of electrons with seasaw geometry. ClO2- has three bond pairs of electrons and two lone pairs of electrons with V-shaped geometry.
Hence, i and iv are identical in geometry.