Arrange the following in increasing order of basicity.
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NH3 < PH3 < AsH3 < BiH3
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NH3 < PH3 > AsH3 < BiH3
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BiH3 < SbH3 < AsH3 < PH3 < NH3
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BiH3 < SbH3 < AsH3 > PH3 < NH3
The electronic configuration of N is 1s2 2s2 2p3 . 's' and 'p' orbital of nitrogen atom requires energy in order to for the hybrid orbital . and after that it will combine with three hydrogen atoms in which energy is released which is greater than the energy requires for the formation of hybrid orbital . If this condition is satisfies than only bond is formed . but in case of phosphorus and higher elements these compensation of energy is not that much which compensate the energy of hybridization . hence each P orbital overlap individually & hence there bond angle is around 90 degree and whatever fluctuation about 90 degree is because of replusion . As we move down the group electron will be then donated form pure 's' orbital . Hence, the correct order is BiH3 < SbH3 < AsH3 < PH3 < NH3 .