Which one of the following statement is/are true?
P. B3N3H6 is known as inorganic benzene.
Q. Boric acid is a dibasic acid.
R. Maximum covalence of boron cannot exceed 4.
S. BF3 is a Lewis base.
Select the correct answer using codes given below.
-
P and Q
-
P and S
-
Q and R
-
Q and S
-
R and S
D
Correct answer
Explanation
Boric acid is a weak monobasic acid. It is not a protonic acid but acts as a Lewis acid by accepting electrons from a hydroxyl ion:
B(OH)3 + 2H2O → [B(OH)4]– + H3O+
The number of electrons around the central atom in BF3 is only six. Such electron deficient molecules have tendency to accept a pair of electrons to achieve stable electronic configuration and thus, behave as Lewis acids.