CO2 is transported in blood as carbaminohemoglobin (HbCO2) when bound to hemoglobin's amino groups. This accounts for about 20-30% of CO2 transport. NaHCO3 (sodium bicarbonate) is the main transport form (70%), H2CO3 is carbonic acid (transient), and HbCO is carbon monoxide bound to hemoglobin (a toxin, not normal CO2 transport).