Multiple choice The ionic compound, which crystallises in corundum structure is CaO SrCl2 Li2O ZnS Al2O3 Reveal answer Fill a bubble to check yourself E Correct answer Explanation Corundum structure: Anions form hexagonal closest packing and cations are present in 2 / 3 of the octahedral holes. The general formula of the compound is M2O3. Examples: Fe2O3, Al2O3, Cr2O3, etc.