Sodium bicarbonate (NaHCO3) reacts rapidly with dilute sulfuric acid to produce carbon dioxide gas through acid-base reaction: 2NaHCO3 + H2SO4 → Na2SO4 + 2H2O + 2CO2. This quick CO2 generation makes it ideal for fire extinguishers. Marble, magnesite, and limestone react too slowly for effective emergency use.